期刊
PHYSICAL REVIEW A
卷 87, 期 5, 页码 -出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevA.87.052717
关键词
-
资金
- Russian Foundation for Basic Research [11-03-00081, 13-03-00163]
- Russian Academy of Sciences (Program of the Fundamental Research by Division of Chemistry and Material Sciences
Charge-transfer cold Yb+ + Rb collision dynamics is investigated theoretically using high-level ab initio potential energy curves, dipole moment functions, and nonadiabatic coupling matrix elements. Within the scalar-relativistic approximation, the radiative transitions from the entrance A(1)Sigma(+) to the ground X-1 Sigma(+) state are found to be the only efficient charge-transfer pathway. The spin-orbit coupling does not open other efficient pathways, but alters the potential energy curves and the transition dipole moment for the A-X pair of states. The radiative, as well as the nonradiative, charge-transfer cross sections calculated within the 10(-3)-10 cm(-1) collision energy range exhibit all features of the Langevin ion-atom collision regime, including a rich structure associated with centrifugal barrier tunneling (orbiting) resonances. Theoretical rate coefficients for two Yb isotopes agree well with those measured by immersing Yb+ ions in an ultracold Rb ensemble in a hybrid trap. Possible origins of discrepancy in the product distributions and relations to previously studied similar processes are discussed.
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