期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 15, 期 42, 页码 18539-18548出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cp52870g
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资金
- National Synchrotron Light Source, Brookhaven National Laboratory
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-98CH10886]
- New York State Energy Research and Development Authority [18517]
- Department of Energy, Office of Basic Energy Sciences [DE-SC0002460]
Magnetite (Fe3O4) is an abundant, low cost, environmentally benign material with potential application in batteries. Recently, low temperature coprecipitation methods have enabled preparation of a series of nanocrystalline magnetite samples with a range of crystallite sizes. Electrochemical cells based on Li/Fe3O4 show a linear increase in capacity with decreasing crystallite size at voltages >= 1.2 V where a 2x capacity improvement relative to commercial (26.2 nm) magnetite is observed. In this report, a combination of X-ray powder diffraction (XRD) and X-ray absorption spectroscopy ( XAS) is used to measure magnetite structural changes occurring upon electrochemical reduction, with parent Fe3O4 crystallite size as a variable. Notably, XAS provides evidence of metallic iron formation at high levels of electrochemical reduction.
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