Article
Chemistry, Multidisciplinary
Guillaume Bousrez, Olivier Renier, Brando Adranno, Volodymyr Smetana, Anja-Verena Mudring
Summary: The study found that 1,3-dialkyltriazolium iodides exhibit high chemical and thermal stability, with significant changes in electrolyte properties upon addition of different iodine content, where iodine addition usually leads to a decrease in melting point and an increase in conductivity. Compared to imidazolium iodides, triazolium compounds show higher efficiency and longer battery life, possibly due to their non-hygroscopic nature.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2021)
Article
Chemistry, Physical
Fatima Santos, Jorge Martins, Jeffrey Capitao, Seyedali Emami, Dzmitry Ivanou, Adelio Mendes
Summary: Dye-sensitized solar cells (DSSCs) are a promising technology for wireless powering of low-consuming electronics and sensor nodes of the internet of things (IoT). This study achieved highly stable cobalt-mediated monolithic DSSCs through encapsulation using a glass-frit sealant, eliminating extrinsic degradation factors.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Fatima Santos, Carolina Hora, Dzmitry Ivanou, Adelio M. Mendes
Summary: Due to their high power conversion efficiency under indoor light, dye-sensitized solar cells (DSSCs) are considered a promising energy technology for future IoT devices and wireless sensors. Monolithic design DSSCs offer advantages in commercial production, such as straightforward processing, low cost, and compactness.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Engineering, Electrical & Electronic
Subhrajit Konwar, Pramod K. Singh, Pawan Dhapola, Abhimanyu Singh, Serguei V. Savilov, Muhd Zu Azhan Yahya, Sirin Siyahjani Gultekin, Burak Gultekin
Summary: This paper deals with the synthesis, characterization, and application of low-viscosity ionic liquids as dopants and biopolymers as the host. The ionic liquid enhances the ionic conductivity and thermal stability of the biopolymer electrolyte, leading to the development of highly conducting ionic-liquid-doped biopolymer electrolyte-based devices such as electrochemical double-layer capacitors and dye-sensitized solar cells.
ACS APPLIED ELECTRONIC MATERIALS
(2023)
Article
Chemistry, Physical
Hwan Kyu Masud, Hwan Kyu Kim
Summary: This review discusses advanced polymeric materials developed over the past three decades as matrices of redox electrolytes for quasi-solid-state DSSCs. These optimized and developed polymeric materials can also be potential candidates for various QSS-energy storage fields.
MATERIALS TODAY ENERGY
(2023)
Review
Materials Science, Multidisciplinary
Laura Manceriu, Anil Kumar Bharwal, Nathan Daem, Jennifer Dewalque, Pierre Colson, Frederic Boschini, Rudi Cloots
Summary: Dye-sensitized solar cells (DSSCs) are a promising solution for portable electronics and IoT applications due to their low-cost fabrication and high efficiency. However, the main obstacle to their large-scale exploitation is their limited long-term stability caused by liquid electrolytes. This review summarizes advances in alternative polymer electrolytes, with a focus on polysiloxane-based poly(ionic liquid)s, and evaluates their behavior in DSSCs. The assessment of printability for liquid and gel polymer electrolytes, particularly polysiloxane-based electrolytes, is also discussed.
Article
Energy & Fuels
Simone Galliano, Federico Bella, Matteo Bonomo, Fabrizio Giordano, Michael Gratzel, Guido Viscardi, Anders Hagfeldt, Claudio Gerbaldi, Claudia Barolo
Summary: The study introduces a cobalt-based, jellified aqueous electrolyte with xanthan gum, which achieves an efficiency exceeding 4% in DSSCs. Using design of experiment, the effects of Co2+ concentration, Co2+/Co3+ ratio, and xanthan gum amount modifications on the photovoltaic parameters of lab-scale solar cells were precisely and significantly studied.
Article
Engineering, Electrical & Electronic
Koffi A. Kamenan, Anooja Jagadeesh, N'guessan Raymond Kre, Edja Florentin Assanvo, Suraj Soman, K. N. Narayanan Unni
Summary: A dye sensitized solar cell with a quasi-solid state electrolyte based on natural rubber and iodide electrolyte was successfully fabricated, showing improved power conversion efficiency and hindering back electron transfer. This work opens up possibilities for using natural raw materials in nature-inspired DSSC technology.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2021)
Article
Electrochemistry
Jeanet Conradie
Summary: This mini review briefly discusses the developments on the application of polypyridyl-based copper complexes in dye-sensitized solar cells (DSSCs). Copper complexes can be used as dye sensitizers and/or as redox mediators in DSSCs. The abundance and low cost of copper make it a cheaper and non-toxic alternative to the commonly used iodide/triiodide electrolyte redox couple and the expensive and rare ruthenium-based dyes.
ELECTROCHEMISTRY COMMUNICATIONS
(2022)
Article
Energy & Fuels
Jianfei Lin, Yinglin Wang, Yanan Li, Yuming Shi, Xin Guo, Lingling Wang, Yichun Liu, Xintong Zhang
Summary: By using a chemical cross-linking strategy, high-performance quasi-solid-state DSSCs based on copper have been successfully fabricated. This strategy effectively reduces the crystallinity of polymers inside the gel polymer electrolytes, improving the diffusion coefficient and enhancing the photovoltaic efficiency and open-circuit voltage of the cells.
Article
Materials Science, Multidisciplinary
Mohanraj Kandhasamy, Ganesan Shanmugam, Santhosh Kamaraj, Balamurugan Selvaraj, Ahalya Gunasekeran, Anandan Sambandam
Summary: In dye-sensitized solar cells, copper redox mediator and additives have been investigated for improving power conversion efficiency. This study focuses on the regeneration of N3 dye absorbed in TiO2 using biopolymer-based electrolytes. Different electron-withdrawing substituents on copper complexes are examined for their regeneration behavior. The results show that the devices with CF3 substituent exhibit higher Voc and J(sc), and the device with limonene additive achieves a higher PCE of 4.4%.
MATERIALS TODAY COMMUNICATIONS
(2023)
Article
Chemistry, Physical
Kicheon Yoo, Ashok Kumar Kaliamurthy, Jae-Joon Lee, Min Jae Ko
Summary: The performance of quasi-solid-state dye-sensitized solar cells (qs-DSSCs) using Polyvinylpyrrolidone/Polyethylene glycol (PVP/PEG) blends was investigated over a wide temperature range. The PVP/PEG blend exhibited low glass-transition temperature and high ionic conductivity, leading to high power conversion efficiency (PCE) at both low and ambient temperatures. Additionally, the qs-DSSC with PVP/PEG showed excellent long-term stability.
JOURNAL OF POWER SOURCES
(2023)
Article
Chemistry, Physical
Masud, Haoran Zhou, Hwan Kyu Kim
Summary: Different redox shuttle-mediated polymer gel electrolytes were used to fabricate quasi-solid-state dye-sensitized solar cells for outdoor and indoor applications. The power conversion efficiency of these cells was comparable to liquid electrolyte-devices under various illuminations. The efficiency of cobalt and copper complex-mediated gel electrolytes was particularly high under compact fluorescent light illumination. These findings suggest the potential commercial utilization of metal-complex-mediated gel electrolytes as a safe power source for low-powered electronic devices.
MATERIALS TODAY ENERGY
(2023)
Article
Chemistry, Multidisciplinary
Zijian Deng, Xichuan Yang, Kaiyuan Yang, Li Zhang, Haoxin Wang, Xiuna Wang, Licheng Sun
Summary: Redox mediators are crucial in dye-sensitized solar cells, and copper complexes are a good option, despite electron recombination issues. By synthesizing two helical copper(I) complexes and eliminating the use of 4-(tert-butyl)pyridine, the efficiency of the solar cells was improved. Increasing the concentration of (CuLa)-La-I showed an increase in both photocurrent and photovoltage, leading to the best power conversion efficiency at 8.2%. Further investigation into the relationship between Cu(I) concentration and recombination was conducted for future research.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2021)
Article
Green & Sustainable Science & Technology
Z. L. Goh, Norshahirah M. Saidi, N. K. Farhana, Shahid Bashir, Javed Iqbal, K. Ramesh, S. Ramesh, S. Wageh, Abul Kalam
Summary: In this study, hydroxypropyl cellulose (HPC)-based gel polymer electrolytes with different alkali metal iodide salts were investigated. The addition of potassium iodide (KI) salt resulted in the highest ionic conductivity, followed by sodium iodide (NaI) and lithium iodide (LiI). Furthermore, the incorporation of sonochemically synthesized cobalt oxide (Co3O4) nanoparticles into the KI sample further improved the ionic conductivity, reduced the activation energy and degree of crystallinity of the electrolyte. Dye sensitized solar cells assembled with the developed gel polymer electrolytes showed improved short-circuit current density and efficiency. The electrolyte containing 7 wt% of Co3O4 nanoparticles achieved the best ionic conductivity and photovoltaic performance.
SUSTAINABLE ENERGY TECHNOLOGIES AND ASSESSMENTS
(2022)
Article
Chemistry, Physical
R. Ramarajan, M. Kovendhan, K. Thangaraju, D. Paul Joseph, R. Ramesh Babu, Viswanathan Elumalai
JOURNAL OF ALLOYS AND COMPOUNDS
(2020)
Article
Nanoscience & Nanotechnology
Wei Zhang, Fuguo Zhang, Bo Xu, Yuanyuan Li, Linqin Wang, Biaobiao Zhang, Yu Guo, James M. Gardner, Licheng Sun, Lars Kloo
ACS APPLIED MATERIALS & INTERFACES
(2020)
Article
Chemistry, Physical
Natarajan Arumugam, Abdulrahman I. Almansour, Raju Suresh Kumar, Saied M. Soliman, E. Viswanathan, Necmi Dege, Ponmurugan Karuppiah, Naif Abdullah Al-Dhabi
Summary: A hybrid heterocycle comprising ferrocene, spiropyrrolidine, and quinoxaline structural moieties was synthesized in good yield via ionic liquid expedited multicomponent 1,3-dipolar cycloaddition reaction. Structural properties were studied using single crystal X-ray crystallographic studies, while Fe-C interactions and antimicrobial potential were investigated through NBO and AIM calculations. The compound showed significant antimicrobial activity against E. coli and S. enterica, as well as antioxidant activity with an IC50 value of 33.80 μg/mL.
JOURNAL OF MOLECULAR STRUCTURE
(2021)
Review
Chemistry, Multidisciplinary
Marko Stojanovic, Natalie Flores-Diaz, Yameng Ren, Nikolaos Vlachopoulos, Lukas Pfeifer, Zhongjin Shen, Yuhang Liu, Shaik M. Zakeeruddin, Jovana V. Milic, Anders Hagfeldt
Summary: This review article provides a historical overview of the developments in dye-sensitized solar cells, focusing on the scientific advancements that have set the stage for this technology to emerge and thrive. The article also outlines applications and future perspectives, including the objective of developing efficient solid-state alternatives to conventional dye-sensitized solar cells.
HELVETICA CHIMICA ACTA
(2021)
Review
Energy & Fuels
Michele Morgante, Nick Vlachopoulos, Anders Hagfeldt, Fabian Fischer
Summary: In recent years, significant efforts have been made to find alternative renewable energy sources, with photo-assisted microbial bioelectrochemical cells (MBECs) garnering considerable interest as a potential technology for hydrogen generation. Two main categories, namely systems with a semiconductor photocathode or photoanode and hybrid systems coupling an MBEC cell with dark electrodes to an electrochemical photovoltaic cell, have been investigated. Microorganisms are required at the anode in all these systems to generate an electron flow through organic matter oxidation.
JOURNAL OF PHYSICS-ENERGY
(2021)
Article
Chemistry, Physical
Jiajia Gao, Aleksandar Tot, Haining Tian, James M. Gardner, Dibya Phuyal, Lars Kloo
Summary: Electrochemical impedance spectroscopy (EIS) was used to study the ageing mechanism of dye-sensitized solar cells (DSSCs). The findings showed that the lack of sufficient redox complexes was the main cause of decreased performance after ageing. Additionally, high-resolution fluorescence detected X-ray absorption spectroscopy (HERFD-XAS) revealed the reduction of Co(iii) to Co(ii) during ageing.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Review
Chemistry, Multidisciplinary
Nick Vlachopoulos, Michael Gratzel, Anders Hagfeldt
Summary: This review introduces the application of electronically conducting polymers as hole conductors in solid-state dye solar cells. It covers the basic principles of dye solar cell operation, electrochemical polymerization, and different configurations of S-DSSCs.
Review
Chemistry, Physical
Fatima Haydous, James M. Gardner, Ute B. Cappel
Summary: Metal halide perovskites are attractive materials for solar cells and optoelectronic devices due to their impressive properties. Perovskite nanocrystals have high quantum yield and tunable emission wavelength, making them ideal candidates for applications.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Chemistry, Multidisciplinary
Xiong Xiao, Billy W. Hoogendoorn, Yiqian Ma, Suchithra Ashoka Sahadevan, James M. Gardner, Kerstin Forsberg, Richard T. Olsson
Summary: An ultrasound-assisted extraction method was used to extract valuable metals from discarded lithium-ion batteries. It was found that using citric or acetic acid as the leaching agent, combined with ultrasound leaching, improved the efficiency of metal dissolution. The study showed that ultrasound leaching enhanced metal dissolution and facilitated a more environmentally friendly recovery of metals from batteries.
Article
Materials Science, Multidisciplinary
Bhushan P. Kore, Wei Zhang, Billy W. Hoogendoorn, Majid Safdari, James M. Gardner
Summary: Long-chain alkylammonium cation-based 2D perovskites are effective coatings for 3D perovskites in improving stability and performance of perovskite solar cells, with only a 20% drop in power conversion efficiency after six months of operation in a humid environment.
COMMUNICATIONS MATERIALS
(2021)
Review
Chemistry, Multidisciplinary
Sandy Sanchez, Lukas Pfeifer, Nikolaos Vlachopoulos, Anders Hagfeldt
Summary: The use of a solution process to grow perovskite thin films extends material processability and allows tuning of physicochemical properties by controlling crystal growth. Controlling crystal growth with rapid thermal annealing and high-precision photonic sintering simplifies experimental frameworks, opening up new synthesis methods. This knowledge improves perovskite synthesis and thin film quality, leading to higher device performances.
CHEMICAL SOCIETY REVIEWS
(2021)
Article
Chemistry, Multidisciplinary
Andrey Shatskiy, Anton Axelsson, Elena V. Stepanova, Jian-Quan Liu, Azamat Z. Temerdashev, Bhushan P. Kore, Bjorn Blomkvist, James M. Gardner, Peter Diner, Markus D. Karkas
Summary: A protocol for stereoselective C-radical addition to a chiral glyoxylate-derived N-sulfinyl imine was developed through visible light-promoted photoredox catalysis, providing a convenient method for the synthesis of unnatural alpha-amino acids. The protocol allows the use of ubiquitous carboxylic acids as radical precursors without prior derivatization. Alternative mechanisms for the developed transformation are discussed and corroborated by experimental and computational studies.
Article
Chemistry, Physical
Nick Vlachopoulos, Anders Hagfeldt, Iacopo Benesperi, Marina Freitag, Ghufran Hashmi, Guobin Jia, Ruri Agung Wahyuono, Jonathan Plentz, Benjamin Dietzek
Summary: This paper discusses issues related to the current direction of DSSC research, focusing on the transition from iodide-containing electrolyte to alternative CTMs, introducing new dyes and counter electrodes in the process. The recent developments of CTMs based on Cu coordination complexes and their associated novel dyes are discussed in detail.
SUSTAINABLE ENERGY & FUELS
(2021)
Article
Electrochemistry
J. Arockia Selvi, M. Arthanareeswari, P. Kamaraj, T. Pushpa Malini, V Elumalai, S. Revathi, N. Subasree
PORTUGALIAE ELECTROCHIMICA ACTA
(2020)
Article
Chemistry, Physical
Sergey Yu. Ketkov, Sheng-Yuan Tzeng, Elena A. Rychagova, Anton N. Lukoyanov, Wen-Bih Tzeng
Summary: Metallocenes, including methylcobaltocene, play important roles in various fields of chemistry. The ionization energy and vibrational structure of (Cp ')(Cp)Co can be influenced by introducing methyl substituents. The mass-analyzed threshold ionization spectrum and DFT calculations provide accurate information about the properties and transformations of (Cp ')(Cp)Co.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Review
Chemistry, Physical
Qifeng Mu, Jian Hu
Summary: Polymer mechanochemistry has experienced a renaissance due to the rapid development of mechanophores and principles governing mechanochemical transduction or material strengthening. It has not only provided fundamental guidelines for converting mechanical energy into chemical output, but also found applications in engineering and smart devices.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Da Hye Yang, Francesco Ricci, Fredrik L. Nordstrom, Na Li
Summary: Through systematic evaluation of the oiling-out behavior of procaine, we identified both stable and metastable liquid-liquid phase separation, and established phase diagrams to assist in rational selection of crystallization strategies.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Vikki Anand Varma, Simmie Jaglan, Mohd Yasir Khan, Sujin B. Babu
Summary: Designing engineering structures like nanocages, shells, and containers through self-assembly of colloids is a challenging problem. This work proposes a simple model for the subunit, which leads to the formation of monodispersed spherical cages or containers. The model with only one control parameter can be used to design cages with the desired radius.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Hainan Jiang, Yaolong He, Xiaolin Li, Zhiyao Jin, Huijie Yu, Dawei Li
Summary: The cycling lifespan and coulombic efficiency of lithium-ion batteries are crucial for high C-rate applications. The Li-ion concentration plays a crucial role in determining the mechanical integrity and structural stability of electrodes. This study focuses on graphite as the working electrode and establishes an experimental system to investigate the mechanical properties of composite graphite electrode at different C-rates. Considering the effect of Li-ion concentration in stress analysis is found to be significant.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Zhiye Wang, Yunchuan Li, Mingjun Sun
Summary: This study investigates the influence of intramolecular pi-pi interactions on the electronic transport capabilities of molecules. By designing and analyzing three pi-conjugated molecules, the researchers observe that different pi-conjugated structures have varying effects on electron transport. The findings provide a theoretical foundation for designing single-molecule electronic devices with multiple electron channels based on intramolecular pi-pi interactions.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Yuandong Xu, Haoyang Feng, Chaoyang Dong, Yuqing Yang, Meng Zhou, Yajun Wei, Hui Guo, Yaqing Wei, Jishan Su, Yingying Ben, Xia Zhang
Summary: Hollow MoS2 cubes and spheres were successfully synthesized using a one-step hydrothermal method with the hard template method. The hollow MoS2 cubes exhibited higher specific capacitance and energy density compared to the hollow MoS2 spheres. The symmetrical supercapacitors assembled with these hollow structures showed good performance and high capacity retention after multiple cycles. These findings suggest that controlling the pore structure and surface characteristics of MoS2 is crucial for enhancing its electrochemical properties.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Ainhoa Oliden-Sanchez, Rebeca Sola-Llano, Joaquin Perez-Pariente, Luis Gomez-Hortiguela, Virginia Martinez-Martinez
Summary: The combination of photoactive molecules and inorganic structures is important for the development of advanced materials in optics. In this study, bulky dyes were successfully encapsulated in a zeolitic framework, resulting in emission throughout the visible spectrum.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Miaomiao Zhang, Cunyuan Pei, Qiqi Xiang, Lintao Liu, Zhongxu Dai, Huijuan Ma, Shibing Ni
Summary: The design of a solid electrolyte interphase (SEI) plays a crucial role in improving the electrochemical performance of anode materials. In this study, lithium difluoro(oxalate)borate (LiDFOB) is used as an electrolyte additive to form a protective SEI film on Li3VO4 (LVO) anodes. The addition of LiDFOB results in a dense, uniform, stable, and LiF-richer SEI, which enhances the Li-ion storage kinetics. The generated SEI also prevents further decomposition of the electrolyte and maintains the morphology of LVO anodes during charge/discharge processes. This work demonstrates the effectiveness of LiDFOB as a multi-functional additive for LiPF6 electrolytes and provides insights into SEI construction for high-performance LVO anodes.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
B. V. Andryushechkin, T. V. Pavlova, V. M. Shevlyuga
Summary: The atomic structure of the Ag(111)-p(4 x 4)-O phase was reexamined and two phases with the same periodicity were discovered. It was demonstrated that the accepted Ag6 model is incompatible with high-resolution oxygen-sensitive STM images.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
S. L. Romo-Avila, D. Marquez-Ruiz, R. A. Guirado-Lopez
Summary: In this study, we used density functional theory (DFT) calculations to investigate the interaction between model graphene oxide (GO) nanostructures and chlorine monoxide ClO. We aimed to understand the role of this highly oxidizing species in breaking C-C bonds and forming significant holes on GO sheets. Our results showed that C-C bonds in a single graphene oxide sheet can be broken through a simple mechanism involving the dissociation of two chemically attached ClO molecules. The formation of carbonyl groups and holes on the GO surface was also observed. This study provides important insights into the degradation of carbon nanotubes and the stability of GO during the myeloperoxidase (MPO) catalytic cycle.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Alberto Garcia-Fernandez, Birgit Kammlander, Stefania Riva, Hakan Rensmo, Ute B. Cappel
Summary: In this study, the X-ray stability of five different lead halide perovskite compositions (MAPbI3, MAPbCl3, MAPbBr3, FAPbBr3, CsPbBr3) was investigated using photoelectron spectroscopy. Different degradation mechanisms and resistance to X-ray were observed depending on the crystal composition. Overall, perovskite compositions based on the MA+ cation were found to be less stable than those based on FA+ or Cs+. Metallic lead formation was most easily observed in the chloride perovskite, followed by bromide, and very little in MAPbI3. Multiple degradation processes were identified for the bromide compositions, including ion migration, formation of volatile and solid products, as well as metallic lead. CsBr was formed as a solid degradation product on the surface of CsPbBr3.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Timofei Rostilov, Vadim Ziborov, Alexander Dolgoborodov, Mikhail Kuskov
Summary: The shock-loading behavior of nanomaterials is investigated in this study. It is found that shock compaction waves exhibit a distinct two-step structure, with the formation of faster precursor waves that travel ahead of the main compaction waves. The complexity of the shock Hugoniot curve of the tested nanomaterial is described, and the effect of initial porosity on the compressed states is demonstrated.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Sergey S. Nikitin, Alexander D. Koryakov, Elizaveta A. Antipinskaya, Alexey A. Markov, Mikhail V. Patrakeev
Summary: The stability of La1/3Sr2/3Fe1-xMnxO3-delta, a perovskite-type oxide, under reducing conditions is dependent on the manganese content. Increasing the manganese content leads to a decrease in stability. The behavior of iron and manganese in the oxide shows distinct differences, which can be attributed to the difference in the enthalpy of oxidation reactions. Additionally, the change in the La/Sr ratio affects the concentration of iron and manganese ions.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Mosayeb Naseri, Shirin Amirian, Mehrdad Faraji, Mohammad Abdur Rashid, Maicon Pierre Lourenco, Venkataraman Thangadurai, D. R. Salahub
Summary: Inspired by the successful transfer of freestanding ultrathin films of SrTiO3 and BiFeO3, this study assessed the structural stability and investigated the electronic, optical, and thermoelectric properties of a group of two-dimensional perovskite-type materials called perovskenes. The findings revealed that these materials are wide bandgap semiconductors with potential application in UV shielding. Moreover, they exhibit better electrical and thermal conductivity at high temperatures, enabling efficient power generation in thermoelectric devices.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)