期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 14, 期 24, 页码 8506-8510出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cp40629b
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资金
- Natural Science Foundation of China (NSFC) [20973100, 21133009]
The selective recognition between CB[7] and hexadecyl dimethyl benzyl ammonium chloride (HDBAC) was investigated using ITC and NMR. The long alkyl-bearing surfactant can form micelles when dispersed in water. We found that progressive addition of CB[7] into the HDBAC dispersion induced the transformation of micelles into various self-organized structures including nanorods and nanosheets as evidenced by DLS, TEM, AFM and SAXS. A rational mechanism is proposed to illustrate the host-guest interaction induced transformation process.
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