Review
Biology
Melissa S. F. Ng, Leonard Tan, Quanbo Wang, Charles R. Mackay, Lai Guan Ng
Summary: Neutrophils are increasingly recognized for their role in cancer, but their immunosuppressive and pro-tumorigenic functions pose challenges for potential therapies. Inhibition or depletion of neutrophils are being explored, but unresolved questions remain regarding their diversification and potential anti-tumor roles.
SCIENCE CHINA-LIFE SCIENCES
(2021)
Review
Virology
Malik Peiris, Stanley Perlman
Summary: The Middle East Respiratory Syndrome-coronavirus (MERS-CoV) primarily spreads to humans through dromedary camels in Africa, the Middle East, and Central or South Asia, with limited human-to-human transmission. Only cases in humans from the Arabian Peninsula have been reported so far, and no zoonotic MERS cases have been found in Africa or Asia, despite the high density of infected camels. Further investigation into this disparity is crucial due to the pandemic potential of MERS-CoV.
CURRENT OPINION IN VIROLOGY
(2022)
Editorial Material
Biotechnology & Applied Microbiology
Michael Francisco
Summary: A trailblazer in the field of spatially resolved transcriptomics and genomics methods shares her transformation from a professional ice hockey player to leading her own research laboratory.
NATURE BIOTECHNOLOGY
(2023)
Editorial Material
Biotechnology & Applied Microbiology
Julie Chuong
Summary: An expert in network dynamics and cell interactions shares her experience of interdisciplinary background, creativity, and creating a sense of community in her lab, especially during the pandemic.
NATURE BIOTECHNOLOGY
(2023)
News Item
Multidisciplinary Sciences
Heidi Ledford
Summary: Safety concerns have led to delays in the use of two COVID-19 vaccines, prompting scientists to seek answers to important questions.
Editorial Material
Biochemistry & Molecular Biology
Meghie Rodrigues, Simon Manga
Summary: Early-career researchers discuss their top priorities in cancer research, which include early screening and immunotherapy, as well as the significance of nanotechnology and counseling.
News Item
Multidisciplinary Sciences
Ewen Callaway
Summary: As the first clinical trials in young children begin, scientists are focusing on what they want to learn from these trials.
Editorial Material
Multidisciplinary Sciences
Andreas Goldthau, Simone Tagliapietra
Summary: Market turmoil and geopolitical realignment caused by Russia's invasion of Ukraine have put both livelihoods and the green-energy transition at risk. Researchers can play a vital role in overcoming these threats.
Article
Nutrition & Dietetics
Silvia Burlina, Maria Grazia Dalfra, Annunziata Lapolla
Summary: Obesity is increasing in women of childbearing age, with prevalence varying in different regions of Europe. Nutritional intake after bariatric surgery depends on surgery type, symptoms, and complications. Monitoring and managing nutrition in pregnancy following bariatric surgery is necessary to prevent deficiencies in each trimester.
Article
International Relations
Giacomo Delledonne
Summary: The review article discusses three books that analyze recent trends in the institutional architecture of the European Union, focusing on legislative-executive relations, self-empowerment strategies of the European Parliament, and leadership performance of the President of the European Commission. It points out the impact of the crises in the past decade on the EU institutions and emphasizes the importance of considering the composite nature of the European constitution and the interplay of formal and informal institutional change in its evolution.
JOURNAL OF EUROPEAN INTEGRATION
(2021)
Review
Ecology
Isabelle Marechaux, Fanny Langerwisch, Andreas Huth, Harald Bugmann, Xavier Morin, Christopher P. O. Reyer, Rupert Seidl, Alessio Collalti, Mateus Dantas de Paula, Rico Fischer, Martin Gutsch, Manfred J. Lexer, Heike Lischke, Anja Rammig, Edna Rodig, Boris Sakschewski, Franziska Taubert, Kirsten Thonicke, Giorgio Vacchiano, Friedrich J. Bohn
Summary: This article discusses the value of forest models in advancing our understanding of forest ecosystems and presents key questions that can be addressed with these models in the next decade. Using species distribution models, individual-based forest models, and dynamic global vegetation models as examples, it demonstrates how models have evolved to tackle current important ecological topics.
ECOLOGY AND EVOLUTION
(2021)
Article
Multidisciplinary Sciences
Michael Benedict Davies, Martin Fitzner, Angelos Michaelides
Summary: Through molecular dynamics simulations, researchers have found that many different substrates can promote the formation of pristine I-c, I-c can be selectively nucleated even with mild supercooling, the water contact layer's resemblance to a face of ice is the key factor determining the polytype selectivity and nucleation temperature, and substrate lattice match to ice is not indicative of the polytype obtained.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
(2021)
Article
Meteorology & Atmospheric Sciences
Yafei Nie, Petteri Uotila, Bin Cheng, Francois Massonnet, Noriaki Kimura, Andrea Cipollone, Xianqing Lv
Summary: This study calculates sea ice concentration (SIC) budgets for the Southern Ocean using five ocean-sea ice reanalyses and compares them with observations. The assimilation of SIC improves the representation of sea ice extent and area in the reanalysis products. However, the differences in the budgets of SIC changes are influenced by atmospheric and oceanic forcings, as well as model configurations. The results suggest that future reanalyses should focus on improving the modeling of sea ice velocities.
Review
Medicine, Research & Experimental
Benjamin N. Koleske, William R. Jacobs, William R. Bishai
Summary: The complete genome sequence of Mycobacterium tuberculosis, achieved in 1998, has provided invaluable insights and tools for understanding tuberculosis. Whole-genome sequencing has improved our ability to predict antibacterial susceptibility and track epidemics. It also helps in studying the effectiveness of TB vaccines and identifying targets for new treatments.
JOURNAL OF CLINICAL INVESTIGATION
(2023)
Review
Astronomy & Astrophysics
Hitesh G. Changela, Elias Chatzitheodoridis, Andre Antunes, David Beaty, Kristian Bouw, John C. Bridges, Klara Anna Capova, Charles S. Cockell, Catharine A. Conley, Ekaterina Dadachova, Tiffany D. Dallas, Stefaan de Mey, Chuanfei Dong, Alex Ellery, Martin Ferus, Bernard Foing, Xiaohui Fu, Kazuhisa Fujita, Yangting Lin, Sohan Jheeta, Leon J. Hicks, Sen Hu, Akos Kereszturi, Alexandros Krassakis, Yang Liu, Juergen Oberst, Joe Michalski, P. M. Ranjith, Teresa Rinaldi, David Rothery, Hector A. Stavrakakis, Laura Selbmann, Rishitosh K. Sinha, Alian Wang, Ken Williford, Zoltan Vaci, Jorge L. Vago, Michael Waltemathe, John E. Hallsworth
Summary: Mars exploration involves various aspects such as the origin of life, planetary protection, underground microbial activity, and other issues. However, key questions remain unanswered, such as the interpretation of surface features on Mars, the origin of organic macromolecules, and the detection of underground microbial activity.
INTERNATIONAL JOURNAL OF ASTROBIOLOGY
(2021)
Article
Astronomy & Astrophysics
Ester Antonucci, Marco Romoli, Vincenzo Andretta, Silvano Fineschi, Petr Heinzel, J. Daniel Moses, Giampiero Naletto, Gianalfredo Nicolini, Daniele Spadaro, Luca Teriaca, Arkadiusz Berlicki, Gerardo Capobianco, Giuseppe Crescenzio, Vania Da Deppo, Mauro Focardi, Fabio Frassetto, Klaus Heerlein, Federico Landini, Enrico Magli, Andrea Marco Malvezzi, Giuseppe Massone, Radek Melich, Piergiorgio Nicolosi, Giancarlo Noci, Maurizio Pancrazzi, Maria G. Pelizzo, Luca Poletto, Clementina Sasso, Udo Schuehle, Sami K. Solanki, Leonard Strachan, Roberto Susino, Giuseppe Tondello, Michela Uslenghi, Joachim Woch, Lucia Abbo, Alessandro Bemporad, Marta Casti, Sergio Dolei, Catia Grimani, Mauro Messerotti, Marco Ricci, Thomas Straus, Daniele Telloni, Paola Zuppella, Frederic Auchere, Roberto Bruno, Angela Ciaravella, Alain J. Corso, Miguel Alvarez Copano, Regina Aznar Cuadrado, Raffaella D'Amicis, Reiner Enge, Alessio Gravina, Sonja Jejcic, Philippe Lamy, Alessandro Lanzafame, Thimo Meierdierks, Ioanna Papagiannaki, Hardi Peter, German Fernandez Rico, Mewael Giday Sertsu, Jan Staub, Kanaris Tsinganos, Marco Velli, Rita Ventura, Enrico Verroi, Jean-Claude Vial, Sebastien Vives, Antonio Volpicelli, Stephan Werner, Andreas Zerr, Barbara Negri, Marco Castronuovo, Alessandro Gabrielli, Roberto Bertacin, Rita Carpentiero, Silvia Natalucci, Filippo Marliani, Marco Cesa, Philippe Laget, Danilo Morea, Stefano Pieraccini, Paolo Radaelli, Paolo Sandri, Paolo Sarra, Stefano Cesare, Felice Del Forno, Ernesto Massa, Mauro Montabone, Sergio Mottini, Daniele Quattropani, Tiziano Schillaci, Roberto Boccardo, Rosario Brando, Arianna Pandi, Cristian Baietto, Riccardo Bertone, Alberto Alvarez-Herrero, Pilar Garcia Parejo, Maria Cebollero, Mauro Amoruso, Vito Centonze
ASTRONOMY & ASTROPHYSICS
(2020)
Review
Chemistry, Multidisciplinary
Ivan G. Clayson, Daniel Hewitt, Martin Hutereau, Tom Pope, Ben Slater
ADVANCED MATERIALS
(2020)
Article
Multidisciplinary Sciences
Hariom Jani, Jheng-Cyuan Lin, Jiahao Chen, Jack Harrison, Francesco Maccherozzi, Jonathon Schad, Saurav Prakash, Chang-Beom Eom, A. Ariando, T. Venkatesan, Paolo G. Radaelli
Summary: In the quest for post-CMOS technologies, researchers have shown promising results in experimenting with topologically protected ferromagnetic whirls such as skyrmions and their anti-particles, which can serve as solitonic information carriers. Antiferromagnetic analogues have become the subject of intense focus due to their predicted relativistic dynamics and potential for fast deflection-free motion and size scaling, although experimental demonstration in natural antiferromagnetic systems has yet to be achieved. By utilizing a first-order analogue of the Kibble-Zurek mechanism, a family of topological antiferromagnetic spin textures has been stabilized on an Earth-abundant oxide insulator, showing potential for low-energy antiferromagnetic spintronics at room temperature.
Article
Multidisciplinary Sciences
Hariom Jani, Jiajun Linghu, Sonu Hooda, Rajesh V. Chopdekar, Changjian Li, Ganesh Ji Omar, Saurav Prakash, Yonghua Du, Ping Yang, Agnieszka Banas, Krzysztof Banas, Siddhartha Ghosh, Sunil Ojha, G. R. Umapathy, Dinakar Kanjilal, A. Ariando, Stephen J. Pennycook, Elke Arenholz, Paolo G. Radaelli, J. M. D. Coey, Yuan Ping Feng, T. Venkatesan
Summary: Researchers demonstrate the reversible ionic control of the magnetic anisotropy and spin reorientation transition in hematite by incorporating and removing hydrogen, providing insights for future applications in antiferromagnetic spintronics.
NATURE COMMUNICATIONS
(2021)
Article
Chemistry, Physical
Alexander J. Knight, Juliane Borchert, Robert D. J. Oliver, Jay B. Patel, Paolo G. Radaelli, Henry J. Snaith, Michael B. Johnston, Laura M. Herz
Summary: Mixed-halide perovskite films of MAPb(Br0.5I0.5)(3) and FA(0.83)Cs(0.17)Pb(Br0.4I0.6)(3) exhibit clear differences in compositional and optoelectronic changes associated with halide segregation. MAPb(Br0.5I0.5)(3) shows low-barrier ionic pathways that enhance stability against halide segregation, while FA(0.83)Cs(0.17)Pb(Br0.4I0.6)(3) lacks such pathways and undergoes considerable ionic rearrangement under prolonged illumination.
ACS ENERGY LETTERS
(2021)
Article
Chemistry, Physical
Laura Schade, Suhas Mahesh, George Volonakis, Marios Zacharias, Bernard Wenger, Felix Schmidt, Sameer Vajjala Kesava, Dharmalingam Prabhakaran, Mojtaba Abdi-Jalebi, Markus Lenz, Feliciano Giustino, Giulia Longo, Paolo G. Radaelli, Henry J. Snaith
Summary: The introduction of indium cation in the Cs2AgBi1-xInxBr6 crystal structure shrinks the lattice and shifts the phase transition point to lower temperatures. This leads to wider band gaps and improved optoelectronic performance, despite the unfavorable band gap shift.
ACS ENERGY LETTERS
(2021)
Article
Chemistry, Physical
Zainab Sharif, Jacob J. Shephard, Ben Slater, Craig L. Bull, Martin Hart, Christoph G. Salzmann
Summary: This study investigates the effect of ammonium fluoride doping on the transition from Ice III to Ice IX, revealing changes in lattice constants and negative thermal expansion during hydrogen ordering. The research demonstrates how doping induces additional hydrogen disorder and highlights the significance of dopants in exploring the phase diagram of water and the complex solid-state chemistry of ice.
JOURNAL OF CHEMICAL PHYSICS
(2021)
Article
Chemistry, Physical
Christoph G. Salzmann, Alexander Rosu-Finsen, Zainab Sharif, Paolo G. Radaelli, John L. Finney
Summary: Ice V is a structurally complex material with hydrogen ordering affected by doping, systematic examination of various space groups and ordered configurations, and a small increase in volume during hydrogen ordering, which leads to slower kinetics under pressure.
JOURNAL OF CHEMICAL PHYSICS
(2021)
Article
Multidisciplinary Sciences
Quinn D. Gibson, Tianqi Zhao, Luke M. Daniels, Helen C. Walker, Ramzy Daou, Sylvie Hebert, Marco Zanella, Matthew S. Dyer, John B. Claridge, Ben Slater, Michael W. Gaultois, Furio Cora, Jonathan Alaria, Matthew J. Rosseinsky
Summary: By controlling the spatial arrangement of chemical interfaces, vibrational modes can be synergically modified to minimize thermal conductivity.
Article
Nanoscience & Nanotechnology
Doried Ghader, Heng Gao, Paolo G. Radaelli, Alessandra Continenza, Alessandro Stroppa
Summary: The intriguing magnetic behavior of two-dimensional chromium trihalide materials and the potential for spintronics and magnonics are studied. Different stacking in (CrBr3/CrI3) hetero-bilayers can result in different magnetic properties. Optical generation and electric detection of pure magnon spin currents as well as simultaneous realization of magnon spin currents and topological domain walls are proposed. The advantages of (CrBr3/CrI3) hetero-bilayers over (CrI3)(2) homo-bilayers in realizing magnon spin currents are highlighted.
ACS APPLIED NANO MATERIALS
(2022)
Article
Multidisciplinary Sciences
Emily G. Meekel, Ella M. Schmidt, Lisa J. Cameron, A. David Dharma, Hunter J. Windsor, Samuel G. Duyker, Arianna Minelli, Tom Pope, Giovanni Orazio Lepore, Ben Slater, Cameron J. Kepert, Andrew L. Goodwin
Summary: Truchet tilings are a type of tile arrangement that can form aperiodic and labyrinthine patterns. Researchers have discovered that a crystalline metal-organic framework can serve as an atomic-scale realization of a three-dimensional Truchet tiling, exhibiting both non-periodic and ordered yet disordered characteristics.
Article
Materials Science, Multidisciplinary
Kunihiro Yananose, Paolo G. Radaelli, Mario Cuoco, Jaejun Yu, Alessandro Stroppa
Summary: This study reveals the unique physical phenomena of twisted homo-bilayers of collinear antiferromagnetic CrI3. The twisting activates the pyroelectricity and the magneto-optical Kerr effect, which can be controlled by the twist angle to manipulate the electric polarization and Kerr angle.
Article
Chemistry, Multidisciplinary
Daniel Hewitt, Tom Pope, Misbah Sarwar, Alessandro Turrina, Ben Slater
Summary: By using high-throughput screening, eight hypothetical zeolite topologies with significantly higher selectivity for meta-xylene than the existing zeolite ZSM-5 were discovered. These promising materials may provide an impetus for synthetic efforts and could potentially achieve significant energy savings with lower operating temperatures.
Article
Materials Science, Multidisciplinary
Jack Harrison, Hariom Jani, Paolo G. Radaelli
Summary: This study explores topological structures in A-type antiferromagnets, focusing on the candidate material α-Fe2O3 for antiferromagnetic spintronics. By utilizing interfacial Dzyaloshinskii-Moriya interaction, the researchers stabilize a variety of topological textures, including previously undiscovered AFM skyrmions, and provide a scaling model for texture sizes based on simple dimensional analysis.
Article
Engineering, Electrical & Electronic
Giuseppe Virone, Giuseppe Addamo, Ada Vittoria Bosisio, Mario Zannoni, Luca Valenziano, Davide Rizzo, Paolo Radaelli
Summary: The evaluation of the Metop-SG microwave imager radiometric performance is based on thermal vacuum tests with large calibration targets. The modeling approach developed in this article addresses thermal gradients and proximity to the baffle. The uncertainty budget provides low 1-sigma error levels for the cold target brightness temperature.
IEEE JOURNAL OF SELECTED TOPICS IN APPLIED EARTH OBSERVATIONS AND REMOTE SENSING
(2021)
Article
Chemistry, Physical
Sergey Yu. Ketkov, Sheng-Yuan Tzeng, Elena A. Rychagova, Anton N. Lukoyanov, Wen-Bih Tzeng
Summary: Metallocenes, including methylcobaltocene, play important roles in various fields of chemistry. The ionization energy and vibrational structure of (Cp ')(Cp)Co can be influenced by introducing methyl substituents. The mass-analyzed threshold ionization spectrum and DFT calculations provide accurate information about the properties and transformations of (Cp ')(Cp)Co.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Review
Chemistry, Physical
Qifeng Mu, Jian Hu
Summary: Polymer mechanochemistry has experienced a renaissance due to the rapid development of mechanophores and principles governing mechanochemical transduction or material strengthening. It has not only provided fundamental guidelines for converting mechanical energy into chemical output, but also found applications in engineering and smart devices.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Da Hye Yang, Francesco Ricci, Fredrik L. Nordstrom, Na Li
Summary: Through systematic evaluation of the oiling-out behavior of procaine, we identified both stable and metastable liquid-liquid phase separation, and established phase diagrams to assist in rational selection of crystallization strategies.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Vikki Anand Varma, Simmie Jaglan, Mohd Yasir Khan, Sujin B. Babu
Summary: Designing engineering structures like nanocages, shells, and containers through self-assembly of colloids is a challenging problem. This work proposes a simple model for the subunit, which leads to the formation of monodispersed spherical cages or containers. The model with only one control parameter can be used to design cages with the desired radius.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Hainan Jiang, Yaolong He, Xiaolin Li, Zhiyao Jin, Huijie Yu, Dawei Li
Summary: The cycling lifespan and coulombic efficiency of lithium-ion batteries are crucial for high C-rate applications. The Li-ion concentration plays a crucial role in determining the mechanical integrity and structural stability of electrodes. This study focuses on graphite as the working electrode and establishes an experimental system to investigate the mechanical properties of composite graphite electrode at different C-rates. Considering the effect of Li-ion concentration in stress analysis is found to be significant.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Zhiye Wang, Yunchuan Li, Mingjun Sun
Summary: This study investigates the influence of intramolecular pi-pi interactions on the electronic transport capabilities of molecules. By designing and analyzing three pi-conjugated molecules, the researchers observe that different pi-conjugated structures have varying effects on electron transport. The findings provide a theoretical foundation for designing single-molecule electronic devices with multiple electron channels based on intramolecular pi-pi interactions.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Yuandong Xu, Haoyang Feng, Chaoyang Dong, Yuqing Yang, Meng Zhou, Yajun Wei, Hui Guo, Yaqing Wei, Jishan Su, Yingying Ben, Xia Zhang
Summary: Hollow MoS2 cubes and spheres were successfully synthesized using a one-step hydrothermal method with the hard template method. The hollow MoS2 cubes exhibited higher specific capacitance and energy density compared to the hollow MoS2 spheres. The symmetrical supercapacitors assembled with these hollow structures showed good performance and high capacity retention after multiple cycles. These findings suggest that controlling the pore structure and surface characteristics of MoS2 is crucial for enhancing its electrochemical properties.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Ainhoa Oliden-Sanchez, Rebeca Sola-Llano, Joaquin Perez-Pariente, Luis Gomez-Hortiguela, Virginia Martinez-Martinez
Summary: The combination of photoactive molecules and inorganic structures is important for the development of advanced materials in optics. In this study, bulky dyes were successfully encapsulated in a zeolitic framework, resulting in emission throughout the visible spectrum.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Miaomiao Zhang, Cunyuan Pei, Qiqi Xiang, Lintao Liu, Zhongxu Dai, Huijuan Ma, Shibing Ni
Summary: The design of a solid electrolyte interphase (SEI) plays a crucial role in improving the electrochemical performance of anode materials. In this study, lithium difluoro(oxalate)borate (LiDFOB) is used as an electrolyte additive to form a protective SEI film on Li3VO4 (LVO) anodes. The addition of LiDFOB results in a dense, uniform, stable, and LiF-richer SEI, which enhances the Li-ion storage kinetics. The generated SEI also prevents further decomposition of the electrolyte and maintains the morphology of LVO anodes during charge/discharge processes. This work demonstrates the effectiveness of LiDFOB as a multi-functional additive for LiPF6 electrolytes and provides insights into SEI construction for high-performance LVO anodes.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
B. V. Andryushechkin, T. V. Pavlova, V. M. Shevlyuga
Summary: The atomic structure of the Ag(111)-p(4 x 4)-O phase was reexamined and two phases with the same periodicity were discovered. It was demonstrated that the accepted Ag6 model is incompatible with high-resolution oxygen-sensitive STM images.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
S. L. Romo-Avila, D. Marquez-Ruiz, R. A. Guirado-Lopez
Summary: In this study, we used density functional theory (DFT) calculations to investigate the interaction between model graphene oxide (GO) nanostructures and chlorine monoxide ClO. We aimed to understand the role of this highly oxidizing species in breaking C-C bonds and forming significant holes on GO sheets. Our results showed that C-C bonds in a single graphene oxide sheet can be broken through a simple mechanism involving the dissociation of two chemically attached ClO molecules. The formation of carbonyl groups and holes on the GO surface was also observed. This study provides important insights into the degradation of carbon nanotubes and the stability of GO during the myeloperoxidase (MPO) catalytic cycle.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Alberto Garcia-Fernandez, Birgit Kammlander, Stefania Riva, Hakan Rensmo, Ute B. Cappel
Summary: In this study, the X-ray stability of five different lead halide perovskite compositions (MAPbI3, MAPbCl3, MAPbBr3, FAPbBr3, CsPbBr3) was investigated using photoelectron spectroscopy. Different degradation mechanisms and resistance to X-ray were observed depending on the crystal composition. Overall, perovskite compositions based on the MA+ cation were found to be less stable than those based on FA+ or Cs+. Metallic lead formation was most easily observed in the chloride perovskite, followed by bromide, and very little in MAPbI3. Multiple degradation processes were identified for the bromide compositions, including ion migration, formation of volatile and solid products, as well as metallic lead. CsBr was formed as a solid degradation product on the surface of CsPbBr3.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Timofei Rostilov, Vadim Ziborov, Alexander Dolgoborodov, Mikhail Kuskov
Summary: The shock-loading behavior of nanomaterials is investigated in this study. It is found that shock compaction waves exhibit a distinct two-step structure, with the formation of faster precursor waves that travel ahead of the main compaction waves. The complexity of the shock Hugoniot curve of the tested nanomaterial is described, and the effect of initial porosity on the compressed states is demonstrated.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Sergey S. Nikitin, Alexander D. Koryakov, Elizaveta A. Antipinskaya, Alexey A. Markov, Mikhail V. Patrakeev
Summary: The stability of La1/3Sr2/3Fe1-xMnxO3-delta, a perovskite-type oxide, under reducing conditions is dependent on the manganese content. Increasing the manganese content leads to a decrease in stability. The behavior of iron and manganese in the oxide shows distinct differences, which can be attributed to the difference in the enthalpy of oxidation reactions. Additionally, the change in the La/Sr ratio affects the concentration of iron and manganese ions.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Mosayeb Naseri, Shirin Amirian, Mehrdad Faraji, Mohammad Abdur Rashid, Maicon Pierre Lourenco, Venkataraman Thangadurai, D. R. Salahub
Summary: Inspired by the successful transfer of freestanding ultrathin films of SrTiO3 and BiFeO3, this study assessed the structural stability and investigated the electronic, optical, and thermoelectric properties of a group of two-dimensional perovskite-type materials called perovskenes. The findings revealed that these materials are wide bandgap semiconductors with potential application in UV shielding. Moreover, they exhibit better electrical and thermal conductivity at high temperatures, enabling efficient power generation in thermoelectric devices.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)