期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 13, 期 40, 页码 17960-17963出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cp22699a
关键词
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资金
- MEXT, Japan [20108010]
- NRF/MEST, Korea [R31-2008-000-10010-0, 2010-00353]
- Grants-in-Aid for Scientific Research [20108010, 20108001] Funding Source: KAKEN
Bismuth vanadate (BiVO(4)), which is a visible-light responsive heterogeneous photocatalyst, was combined with homogeneous ruthenium complexes to increase the overall photocatalytic reactivity for water oxidation with a one-electron oxidant, [Co(III)(NH(3))(5)Cl](2+). Photoinduced electron transfer from the excited state of ruthenium(II) complexes to [Co(III)(NH(3))(5)Cl](2+) affords ruthenium(III) complexes which can oxidize water to oxygen with BiVO(4) under visible light irradiation.
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