期刊
PHYSICA B-CONDENSED MATTER
卷 407, 期 21, 页码 4244-4250出版社
ELSEVIER
DOI: 10.1016/j.physb.2012.07.009
关键词
Boron-nitride layers; Optical properties; Band structure
资金
- Russian Foundation for Basic Research [11-02-00699-a]
We present an analytic calculation of the optical conductivity of atomically thin hexagonal boron nitride (h-BN) layers in the spectral range where this quantity is expected to be dominated by pi-electron transitions. The approach, which we rely on in this study, is entirely within an independent-particle description of optical response and is based on the tight-binding representation for the pi-electron energy bands of a single h-BN sheet. The most significant result of our calculation is an explicit closed form, in terms of elementary functions, we have found for the real part of the optical conductivity of the h-BN sheet. This allows the optical absorbance of a few-layer h-BN films to be easily evaluated with in the independent-layer approximation. The absorbance is found to be spectrally quite flat (at a level close to zero) up to the threshold frequency (in ultraviolet) corresponding to the onset of resonant interband transitions. Slightly above the threshold, the absorbance exhibits a pronounced sharp symmetric peak reaching similar to 20% in magnitude. This feature as well as the overall spectral profile of the calculated optical absorbance is in good qualitative agreement with experiment. (c) 2012 Elsevier B.V. All rights reserved.
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