期刊
PHYSICA B-CONDENSED MATTER
卷 404, 期 16, 页码 2142-2145出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.physb.2009.04.002
关键词
Ca3Co4O9; Doubly substitution; Grain orientation; Transport properties
资金
- National Natural Science Foundation of China [50702003]
- Beijing Municipal Commission of Education Foundation [JC009001200803]
Doubly substituted polycrystalline compound bulk samples of BaxAgyCa2.8Co4O9 were prepared via citrate acid sol-gel method followed by spark plasma sintering. The phase composition, orientation, texture and high temperature electrical properties were systematically investigated. The results showed that the orientation and the texture could be modified by altering ratio of Ba to Ag. The resistivity and the Seebeck coefficient of substituted samples were decreased by decreasing Ba/Ag ratio except for that of Ba0.1Ag0.1Ca2.8Co4O9 sample with lowest electrical resistivity (7.2 m Omega cm at 973 K), moderately high Seebeck coefficient (172 mu V/K at 973 K) and improved power factor (0.42 mW/mK(2) at 973 K). (C) 2009 Elsevier B.V. All rights reserved.
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