期刊
PETROLEUM SCIENCE AND TECHNOLOGY
卷 32, 期 11, 页码 1349-1356出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/10916466.2012.656871
关键词
propylene; zeolite; methanol to light olefins; mordenite
资金
- Research and Technology Division of the National Iranian Petrochemical Company
Methanol conversion was investigated on dealuminated mordenite (DM) as well as a series of promoted DM (i.e., metal/DM) catalysts prepared by impregnation. Prepared catalysts characterized by the powder XRD, BET, and NH3-TPD techniques. Chemical analysis was performed using induced coupled plasma (ICP) method. The conversion of methanol over different metal/mordenite catalysts was compared at 460 degrees C and WHSV of 1h(-1). Several metals including Fe, La, and Ca had been used to prepare metal/DM catalysts, which displayed high selectivity toward propylene production. Ultimately, La/DM catalyst was determined to be the best material amongst those investigated for methanol conversion based upon its durability and resulting conversion.
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