Article
Chemistry, Physical
Yusuke Kawasaki, Hirofumi Tsukasaki, Tomoji Ayama, Shigeo Mori, Minako Deguchi, Masahiro Tatsumisago, Atsushi Sakuda, Akitoshi Hayashi
Summary: All-solid-state batteries using Li3CuS2 as a sulfide positive electrode active material were operated successfully, showcasing high electronic conductivity.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Jinli Liu, Yingqiang Wu, Bo Zhang, Xiang Xiao, Qiao Hu, Qiaofeng Han, Li Wang, Fengli Bei, Xiangming He
Summary: A solid-state synthesis process for LiMn1-yFeyPO4 (LMFP) was successfully developed. The study revealed that Fe ions diffuse more easily than Mn ions in the olivine framework, and LMFP exhibits good performance and cycling stability. These findings are important for the synthesis and performance improvement of LMFP materials.
Article
Chemistry, Physical
M. A. A. Mohamed, L. Singer, H. Hahn, D. Djendjur, A. Oezkara, E. Thauer, I. G. Gonzalez-Martinez, M. Hantusch, B. Buechner, S. Hampel, R. Klingeler, N. Graessler
Summary: In this study, an antiperovskite (Li2Fe)SeO material was synthesized using a one-step solid-state method. The material showed excellent thermal stability and high cycling performance, making it a promising cathode material for lithium-ion batteries.
JOURNAL OF POWER SOURCES
(2023)
Article
Biochemistry & Molecular Biology
Hechen Li, Yiwen Guo, Yuanhua Chen, Nengshuang Gao, Ruicong Sun, Yachun Lu, Quanqi Chen
Summary: The full-concentration gradient LiNi0.9Co0.083Mn0.017O2 (CG-LNCM) was prepared and compared to concentration-constant LiNi0.9Co0.083Mn0.017O2 (CC-LNCM) in terms of electrochemical performance. CG-LNCM exhibited lower cation mixing and larger Li+ diffusion coefficients, leading to higher capacity and better rate capability and cyclability compared to CC-LNCM. The significantly improved electrochemical performance of CG-LNCM is attributed to its concentration-gradient microstructure and the composition distribution of concentration-gradient LiNi0.9Co0.083Mn0.017O2.
Article
Chemistry, Physical
Lifan Wang, Qinling Shi, Chun Zhan, Guicheng Liu
Summary: In this study, a simple one-step solid-state process was presented for synthesizing Ni-rich ternary cathode materials NCA (LiNi0.9Co0.05Al0.05O2), and the synthesis conditions were systematically studied. It was found that the synthesis conditions have a substantial impact on electrochemical performance. Furthermore, the cathode materials produced through a one-step solid-state process exhibited excellent cycling stability, maintaining 97.2% of their capacity after 100 cycles at a rate of 1 C. The results show that a one-step solid-state method can successfully synthesize Ni-rich ternary cathode material, which has great potential for application. Optimizing the synthesis conditions also provides valuable ideas for the commercial synthesis of Ni-rich cathode materials.
Article
Chemistry, Physical
Tong Wu, Guange Wang, Borui Liu, Qing Huang, Yuefeng Su, Feng Wu, Ryan M. Kelly
Summary: The study successfully synthesized Li (Ni0.8Co0.1Mn0.1)(1-x)CuxO2 (x = 0, 0.005, 0.01 and 0.02) cathode materials and found that copper doping can promote the formation of porous structures on the surface. When x = 0.01, the cathode material exhibited the best electrochemical performance.
JOURNAL OF POWER SOURCES
(2021)
Article
Chemistry, Multidisciplinary
Jiwoong Bae, Xiao Zhang, Xuelin Guo, Guihua Yu
Summary: The development of a high-concentration polymeric interlayer in all-solid-state batteries has shown significant improvement in cycle life and Coulombic efficiency by addressing issues like oxidative vulnerability of solid electrolytes and poor charge transport. The interactions between anions and functional groups in the polymer chain in the high-salt-concentration have led to outstanding physicochemical properties, enabling better utilization of high-energy-density batteries.
Article
Energy & Fuels
Zaowen Zhao, Bao Zhang, Jingtian Zou, Pengfei Li, Zihang Liu, Lei Cheng, Xing Ou, Jiafeng Zhang
Summary: With the increasing demand for electric vehicles, the manufacture of lithium-ion batteries and the consumption of rare resources such as lithium and cobalt are being accelerated. To explore high-efficiency resource reuse, researchers have synthesized high-capacity Ni-rich LiNi0.92Co0.05Mn0.03O2 from a Ni-Co-Cu-Fe alloy powder obtained from recycling spent batteries. The regenerated cathode material exhibits well-crystallized structure and spherical morphology, with promising electrochemical performance.
JOURNAL OF ENERGY STORAGE
(2022)
Article
Electrochemistry
Qingyu Li, Guangchang Yang, Youqi Chu, Chunlei Tan, Qichang Pan, Fenghua Zheng, Yu Li, Sijiang Hu, Youguo Huang, Hongqiang Wang
Summary: The study demonstrates that surface modification with N-doped LiAlO2 greatly enhances the electrochemical performance of LiNi0.6Co0.2Mn0.2O2 cathodes, leading to improved cycling performance and capacity retention. This modification effectively suppresses surface side reactions, structural degradation, and intergranular cracks, showing potential for higher rate operations.
ELECTROCHIMICA ACTA
(2021)
Article
Electrochemistry
David Kitsche, Florian Strauss, Yushu Tang, Nikolai Bartnick, A-Young Kim, Yuan Ma, Christian Kuebel, Juergen Janek, Torsten Brezesinski
Summary: Inorganic solid-state batteries have limitations compared to conventional liquid electrolyte-based lithium-ion batteries. The search for advanced coatings to protect the cathode materials in solid-state batteries is a challenge. This study successfully modified the surface of a Ni-rich cathode material using a sol-gel chemistry method, resulting in improved protection and performance.
BATTERIES & SUPERCAPS
(2022)
Article
Chemistry, Physical
Sung-Beom Kim, Hyeona Kim, Deok-Hye Park, Ji-Hwan Kim, Jae-Hoon Shin, Jae-Sung Jang, Sang-Hyun Moon, Jin-Hyuk Choi, Kyung-Won Park
Summary: Ni-rich cathode materials doped with varying amounts of F using a solid-state reaction method show improved cycling performance due to strong bonding between transition metals and F, as well as enhanced Li+ ion transport behavior. However, when the F doping level exceeds the optimal amount, Li/Ni antisite defects cause deteriorated Li+ ion transport, leading to decreased performance in lithium-ion batteries.
JOURNAL OF POWER SOURCES
(2021)
Article
Chemistry, Physical
Yu Huang, Kai Wu, Ronghui Hao, Wenkang Miao, Yueling Cai, Peng Wang, Jipeng Cheng, Zihan Wang, Qianqian Li, Bingkun Guo, Anmin Nie
Summary: Li2MnO3, as a traditional member of lithium-rich layered cathodes, shows large specific capacity, but suffers from capacity fading and voltage decay. Iridium doping improves electrochemical performance, with dopant concentration and calcination temperature affecting the performance due to intrinsic microstructure and crystallization. The mechanism of improvement lies in the structure stability induced by iridium doping in TM sites, enhancing high-capacity cathode materials for lithium-ion batteries.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Chemistry, Inorganic & Nuclear
M. Akhilash, P. S. Salini, K. Jalaja, Bibin John, T. D. Mercy
Summary: A Li-rich cathode material, Li1.5Ni0.25Mn0.75O2.5, with a well-ordered layered structure was successfully synthesized using a simple carbonate co-precipitation method followed by calcination. SEM analysis showed cylinder-shaped particles with diameter in the range 100-350 nm, and electrochemical evaluation revealed an initial specific capacity of around 240 mAhg(-1) at C/20 rate.
INORGANIC CHEMISTRY COMMUNICATIONS
(2021)
Article
Chemistry, Physical
Jiawei Zheng, Jianwen Yang, Jinmei Wu, Shengxian Li, Mengwen Wang, Bin Huang, Yanwei Li, Shunhua Xiao, Qing Zhu
Summary: Cathode materials LiFe0.5Mn0.5-xYxPO4@C (x = 0, 0.005, 0.01, 0.02, and 0.03) were synthesized and characterized. Y3+ doping led to volume shrinkage, carbon coating, and improved particle size and dispersion. The preferred LiFe0.5Mn0.49Y0.01PO4@C sample exhibited enhanced electrochemical performance with decreased polarization and improved ion diffusion.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Electrochemistry
Ali Yalcin, Muslum Demir, Mehmet Oguz Guler, Mehmet Gonen, Mesut Akgun
Summary: A one-pot approach was used to prepare Sn-doped Li-rich NMC cathode materials for next-generation batteries. The optimized Li-NMC-Sn05 cathode exhibited improved discharge capacity, rate capability, and cyclic performance due to better interface and structural stability as well as reduced ohmic resistance.
ELECTROCHIMICA ACTA
(2023)
Article
Chemistry, Physical
Feng He, Jiahao Zhuang, Bin Lu, Xianglin Liu, Jianling Zhang, Fangna Gu, Minghui Zhu, Jing Xu, Ziyi Zhong, Guangwen Xu, Fabing Su
Summary: The novel Ni-Zr-Al catalysts show superior low-temperature activity in CO2 methanation compared to Ni-Al catalysts and commercial Ni-based catalyst, due to the synergetic effects between Ni and ZrO2 resulting in more surface oxygen vacancies, basic sites, and abundant mesopores. In-situ DRIFTS analysis confirmed the CO2 methanation follows the intermediate formate route, providing a new theoretical understanding for CO2 activation and methanation.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Electrochemistry
Qiongguang Li, Menglei Yuan, Yanhong Wang, Xingyue Gao, Xiaowei Li, Meng Yao, Hongyan He, Qiangqiang Tan, Ziyi Zhong, Fabing Su
Summary: A facile method for preparing chitosan-derived and N-doped carbon composite (Fe-CDNC) decorated with Fe nanoparticles was reported, showing high reversible lithium capacity and cycle stability. The strong coupling between Fe NPs and N-doped carbon layer contributed to outstanding rate performance, cycle stability, and high reversible capacity, promising for the development of novel carbon anode materials for high-energy storage devices.
ELECTROCHIMICA ACTA
(2021)
Review
Energy & Fuels
Suleiman Sabo Bello, Chao Wang, Mengjuan Zhang, He Gao, Zhennan Han, Lei Shi, Fabing Su, Guangwen Xu
Summary: The future of fuel supply will involve the utilization of heavy crude oils, which require initial hydrotreatment for conversion into qualified fuel oils or synthetic crude. The removal of sulfur and nitrogen compounds from heavy crude oils is a critical and challenging part of the upgrading process. However, the mechanisms of these reactions are not fully understood, requiring further research for innovative solutions.
Article
Chemistry, Physical
Qiongguang Li, Yanhong Wang, Xingyue Gao, Huifang Li, Qiangqiang Tan, Ziyi Zhong, Fabing Su
Summary: Novel core-shell structured ZIF-8 derived N-doped carbon/silicon (Si@NC) composites with high reversible capacity and excellent rate performance have been successfully prepared using a modified method. The use of ZIF-8 derived N-doped carbon enhances the lithium storage capability, showing promising application in high energy density LIBs.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Jiahao Zhuang, Feng He, Xianglin Liu, Pengchao Si, Fangna Gu, Jing Xu, Yu Wang, Guangwen Xu, Ziyi Zhong, Fabing Su
Summary: The in situ synthesis of heterophase Ni nanocrystals on graphene, with a heterostructure of face-centered cubic (fcc) and hexagonal close-packed (hcp) phase, showed greatly improved catalytic activity and reusability in 4-nitrophenol reduction. The apparent rate constant and activity parameter were higher than reported non-noble metal and most noble metal catalysts, demonstrating the potential of creating heterophase metal nanocrystals with enhanced catalytic reactivity.
Correction
Chemistry, Physical
R. Jiang, S. Liu, L. Li, Y. Ji, H. Li, X. Guo, L. Jia, Z. Zhong, F. Su
Article
Chemistry, Physical
Shaomian Liu, Yongjun Ji, Wenqing Xu, Jianling Zhang, Ruihuan Jiang, Liang Li, Lihua Jia, Ziyi Zhong, Guangwen Xu, Tingyu Zhu, Fabing Su
Summary: Hierarchically interconnected porous (HIP) MnxCo3-xO4 spinels synthesized by a facile citric acid-assisted sol-gel method show high efficiency as catalysts for CO-DeNO(x), with a wide active-temperature window and enhanced catalytic performance.
JOURNAL OF CATALYSIS
(2022)
Article
Chemistry, Inorganic & Nuclear
Kai Su, Jiachengjun Luo, Yongjun Ji, Xingyu Jiang, Jing Li, Jianling Zhang, Ziyi Zhong, Fabing Su
Summary: The study presented the synthesis of a highly efficient Cu3Si alloy catalyst for silicon hydrochlorination, demonstrating excellent low-temperature catalytic performance. Detailed analysis of the reaction process revealed the significant impact of the charge distribution of Cu and Si atoms in Cu3Si alloy on catalytic performance.
JOURNAL OF SOLID STATE CHEMISTRY
(2021)
Article
Chemistry, Physical
Tengfei Zhang, Peng Zheng, Fangna Gu, Wenqing Xu, Wenxing Chen, Tingyu Zhu, Yi-Fan Han, Guangwen Xu, Ziyi Zhong, Fabing Su
Summary: Hydrogenation of CO2 into CH4 is an effective strategy for dealing with CO2-related environmental issues. The use of a dual-active-site tandem catalyst composed of Ru single atoms and Ni nanoparticles has been found to significantly improve the reaction rate and efficiency of CO2 conversion to CH4.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2023)
Article
Engineering, Chemical
Zhenkun Xia, Jiajian Gao, Tengfei Zhang, Kangjun Wang, Fushan Chen, Guangwen Xu, Ziyi Zhong, Fabing Su
Summary: Inorganicsilicon compounds or products, such as silicon oxides(SiO2), metallurgical silicon (m-Si), silicon carbide (SiC),silicon halides (such as SiH n Cl4-n , n = 0-4 or SiX n , X = F, n = 2; X = Br, n = 4), silicon hydrides (SiH4 and Si2H6), nitrogen compounds (Si3N4),and the others (Si2Cl6 and Si2OCl6), have been remarkably developed in the past years. Understanding the thermodynamics of these reactions is crucial for optimizing reaction conditions and catalyst development. This study comprehensively investigates the thermodynamics of silicon-related reactions and provides valuable insights for industrial applications.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Chemistry, Physical
Heng Zhang, Baofang Jin, Yongxia Zhu, Liqing Ban, Kangjun Wang, Jing Xu, Jiajian Gao, Ziyi Zhong, Guangwen Xu, Fabing Su
Summary: In this study, a series of SnO2-modified commercial Cu2O catalysts with different SnO2 contents were prepared and tested for the Rochow-Muller reaction. It was found that the 0.03SnO2/Cu2O catalyst exhibited the highest dimethyldichlorosilane selectivity and Si conversion. Detailed characterization and analysis revealed that the introduction of SnO2 promoted the transformation of Cu2O to active Cu3Si phase, resulting in the high catalytic performance of the SnO2-modified Cu2O catalysts. This work provides new insights into the promotion of Cu-based catalysts by SnO2 and the catalytic mechanism in the Rochow-Muller reaction.
JOURNAL OF CATALYSIS
(2023)
Article
Chemistry, Physical
Junbo Tian, Peng Zheng, Tengfei Zhang, Zhennan Han, Wenqing Xu, Fangna Gu, Fang Wang, Zhanguo Zhang, Ziyi Zhong, Fabing Su, Guangwen Xu
Summary: In this study, inverse CeO2-Cr2O3/Ni model catalysts were intentionally synthesized to investigate the roles of oxide-metal interfaces in CO2 methanation performance. The results showed that the catalyst with only CeO2-Ni interfaces exhibited a preference for the formate pathway, while the introduction of Cr oxide formed a Cr2O3-Ni interface that altered the nearby CeO2-Ni interface and introduced a CO pathway. The Cr2O3-Ni interface showed a relatively lower CO2 absorption energy and activation energy barrier for CO2 dissociation to CO, leading to excellent low-temperature activity.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2023)
Article
Chemistry, Physical
Xingyue Gao, Yuan Gao, Qiongguang Li, Yanhong Wang, Dawei Zhao, Guangwen Xu, Ziyi Zhong, Fabing Su
Summary: A scalable synthesis method for a carbon-coated SiO(x) composite as anode material for lithium-ion batteries (LIBs) is reported. The SiO(x)/C composite, prepared through the industrial Rochow reaction process, exhibited excellent electrochemical performance and stability. The large-scale production of SiO(x)/C anode material becomes highly feasible by employing an industrial process for alkoxysilane synthesis with controlled reaction conditions.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Qiongguang Li, Yanhong Wang, Jing Yu, Menglei Yuan, Qiangqiang Tan, Ziyi Zhong, Fabing Su
Summary: By synthesizing a superstructure of Si@Co-NC composite, the massive volume expansion of silicon-based anode during charge/discharge cycles can be mitigated, leading to improved electrochemical performance in lithium-ion batteries.
GREEN ENERGY & ENVIRONMENT
(2022)
Article
Chemistry, Physical
Fei Tang, Jing Li, Yongxia Zhu, Yongjun Ji, Huifang Li, Hezhi Liu, Xueguang Wang, Ziyi Zhong, Fabing Su
Summary: This study synthesized cubic Cu/Cu2O hetero-nanoparticles through surface restructuring and used them as model catalysts for the Rochow reaction. It was found that appropriate heterointerfaces can enhance catalytic performance, providing insights into the mechanism of Cu-based catalysts.
CATALYSIS SCIENCE & TECHNOLOGY
(2021)
Article
Engineering, Chemical
Bingyao Wang, Tianyi Cai, Xiaoshu Cai, Wu Zhou, Zeqi Liu
Summary: The size and morphology of nanoparticles significantly impact their performance. Current methods, such as electron microscopy or atomic force microscopy, have limitations in sample preparation, processing time, and quantitative characterization. Therefore, it is crucial to develop a fast, accurate, and statistical method for measuring nanoparticle size and morphology. In this study, a new method called polarized imaging dynamic light scattering (PIDLS) is proposed, which irradiates nanoparticles with a vertical linearly polarized laser beam and utilizes a polarization camera to collect dynamic light scattering images at different polarization directions. The method effectively determines particle size, morphology, and sphericity based on depolarization patterns and degree of linear polarization. PIDLS also enables simultaneous measurement of particle size and morphology distributions, allowing for the evaluation of particle uniformity. The effectiveness of PIDLS is validated with the measurement of five types of industrial titanium dioxide.
Article
Engineering, Chemical
Qingye Meng, Shuangling Zhong, Jingfei Wang, Zhenqian Zhang, Yan Gao, Xuejun Cui
Summary: In this study, a non-toxic natural polysaccharide, sodium alginate (SA), was developed for targeted delivery of curcumin (CUR) in tumor therapy. The CUR was coated in microcapsules using a quick, efficient, and environment-friendly sonochemical method. The microcapsules showed similar toxicity to free curcumin in anti-tumour evaluation and exhibited effective antibacterial properties. This research has the potential to provide a low-cost tumor targeting vector and can be promoted for clinical application.
Article
Engineering, Chemical
Christin Velten, Mirko Ebert, Christian Lessig, Katharina Zaehringer
Summary: Ray tracing Particle Image Velocimetry (RT-PIV) is an optical technique that corrects for distortions in velocity measurements caused by transparent geometries in challenging optical systems. This study focuses on the challenges and implications of using RT-PIV in a body centred cubic (bcc) sphere packing with gaseous flow, where transparent glass balls are used for optical access. The results demonstrate the effectiveness of the method in reconstructing velocity fields behind transparent spheres.
Article
Engineering, Chemical
Yanhao Ye, Ji Xu, Wei Ge
Summary: By modeling neighboring particles as a single coarse-grained particle, the discrete particle method (DPM) can now simulate industrial-scale particle-fluid systems. However, there is still a lack of a systematic approach to determine the properties and interaction models of these coarse-grained particles, which affects the predictability of the method. In this study, kernel functions for modeling the coarse-grained particles are constructed based on the analysis of collisions between predefined particle groups, and the model parameters are determined by equating the statistical properties of the coarse-grained particles to those of the real particles. This approach has been effective in simulating the homogeneous cooling of granular gas and experimental fluidized beds.
Article
Engineering, Chemical
Boris I. Kharisov, Oxana V. Kharissova, Lucy T. Gonzalez, Yolanda Pena Mendez, Igor E. Uflyand, Idalia Gomez de la Fuente
Summary: Hydroxyapatite (HA) composites with carbon allotropes and nanocarbons are rapidly developing in materials chemistry, especially for medical applications. These composites can be synthesized using various methods and exhibit biocompatibility and hemocompatibility, making them suitable for bone regeneration and wastewater treatment.
Article
Engineering, Chemical
Xing Li, Qun Chen, Zhaozhao Liu, Cheng Zhou, Chen Wang, Chen Chen
Summary: The particle size distribution (PSD) curve is an important expression of soil properties. However, existing characteristic parameters can only represent some points of the curve and fail to capture all the information. This paper introduces a new fraction characteristic parameter based on grading entropy and proposes a refined presentation method for the PSD curve. The new method not only represents the differences in curve width more accurately but also has higher discrimination ability. The application of this method in describing deposit distribution and predicting soil hydraulic conductivity is discussed. The research results can provide reference for the refined representation of PSD curves.
Article
Engineering, Chemical
Qingjin Zhang, Liangliang Fu, Guangwen Xu, Dingrong Bai
Summary: This study comprehensively analyzes the temperature effect on the minimum fluidization velocity (Umf) in fluidized-bed reactors. The analysis reveals the influence of temperature on Umf is determined by the relative importance of hydrodynamic forces and interparticle forces, which result in changes in gas properties, bed voidage, and physiochemical characteristics of particles. An equation is derived to predict the temperature influences on Umf under broad temperature conditions.
Article
Engineering, Chemical
Josephine Oppotsch, Matthias Steinke, Miriam Fritsch, Fritz -Herbert Heinsius, Thomas Held, Nikoline Hilse, Viktor Scherer, Ulrich Wiedner
Summary: This work is the second part of a simulation study on processing densely packed and moving granular assemblies using PEPT. A cost-effective PET-like detector system is being developed to overcome the high cost of PET scanners commonly used for PEPT. Monte Carlo simulations and Geant4 software were used to study the spatial resolution of different scenarios, and it was found that oversampling and iteration improved the resolution significantly.
Article
Engineering, Chemical
Lian Duan, Zhixun Xia, Yunchao Feng, Binbin Chen, Likun Ma, Jianxin Hu
Summary: In this study, boron-magnesium agglomerates with varying mass ratios were prepared and the combustion process of these agglomerates under different oxygen-rich concentrations were investigated. The results showed that when the mass fraction of magnesium powder in boron-magnesium agglomerates exceeded a certain threshold, a transient flameout process occurred. This process is affected by the magnesium content of the agglomerate and the oxygen concentration in the ambient atmosphere.
Article
Engineering, Chemical
Lixia Hou, Chunxiao Qu, Min Su, Zhihan Liang, Qi Hao
Summary: This study investigates the impact of polymer modified Fe3O4 nanoparticles on lysozyme (Lys) crystallization under different conditions, using functionalized Fe3O4 magnetic nanoparticles (Polymer C@Fe3O4) as nucleation agents. The findings show that the surface charge density of Polymer C@Fe3O4 is highest at a modification mass ratio of 8:3 for Fe3O4 to Polymer C. By adding 15% of the PolymerC@Fe3O4 prepared from Fe3O4 with an average particle size of 150 nm, magnetic core lysozyme (M-Lys) crystals with an average particle size of 11.08 mm, narrow size distribution, and regular morphology were obtained with a yield of 82.42% within 60 min.
Article
Engineering, Chemical
Fangling Hu, Liangliang Fu, Qingjin Zhang, Guangwen Xu, Dingrong Bai
Summary: This study proposes a method for synthesizing high-quality forsterite using abundant boron mud waste through high-temperature thermochemical reactions. The reaction can be completed rapidly at low temperatures due to the high reactivity of fine raw powder materials. The synthesized forsterite products exhibit high densification, well-developed grains, and an activation energy of 165.5 kJ/mol in the temperature range of 1100-1500°C. This study provides a low-cost method for producing forsterite and an efficient solution for treating solid waste.
Article
Engineering, Chemical
Yi Liu, Yunyan Guo, Rui Zhu, Jinqiang Zhou, Zhengxu Lin, Kai Han, Chongwei An, Jingyu Wang, Bidong Wu
Summary: Improved controllability and energy density of ignition agents are important for the development of energetic composite materials. In this study, HNS/CL-20 composite microspheres were prepared using droplet microfluidics and emulsification techniques with GAP as the binder. The microspheres exhibited higher sphericity and particle size uniformity compared to raw HNS, and retained the crystal structure of both HNS and CL-20. The microspheres also showed higher apparent activation energy, better safety performance, and good dispersibility, demonstrating excellent ignition performance and significant energy release effects.
Article
Engineering, Chemical
Max Kriegeskorte, Nikoline Hilse, Phil Spatz, Viktor Scherer
Summary: This study experimentally analyzed the particle mechanics of a single floor in a multiple hearth furnace. The results showed that increasing the blade angle led to an increase in the particle free surface area. The frequency distribution of the mean distance among particles provided information about the morphology of the particle bulk.
Article
Engineering, Chemical
Min Cai, Shuangzhu Kong, Sheng Chen, Mengxi Liu, Chunxi Lu
Summary: Reasonable reactor design is crucial for increasing the C2 yield in the oxidative coupling of methane (OCM). This study focused on large-scale fluidized bed reactors and conducted experiments and simulations to investigate their hydrodynamics and reaction performance. The results showed that the consecutive reactions of ethylene were severe in the bubbling fluidized bed (BFB) reactor due to gas back-mixing, high solids holdup, and non-uniform solids distribution, while they were negligible in the riser reactor. Both reactors achieved isothermal operation for the OCM process, with the riser reactor showing higher C2 selectivity and yield compared to the BFB reactor. This study provides valuable information for OCM reactor design and commercialization.
Article
Engineering, Chemical
Jiangkui Hu, Shijie Yang, Yingying Pei, Xilong Wang, Yulong Liao, Shuai Li, Aolong Yue, Jia-Qi Huang, Hong Yuan
Summary: This review discusses the interfacial issues in all-solid-state lithium batteries (ASSLBs) based on sulfide solid electrolytes (SEs) and high-voltage cathodes, and proposes strategies to stabilize the electrolyte/cathode interfaces. The future research direction of electrolyte/cathode interfaces and the application prospects of powder technology in sulfide-based ASSLBs are also discussed.