期刊
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
卷 70, 期 -, 页码 4-13出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.trac.2015.01.015
关键词
Aqueous electrolyte; DEMS cell; DEMS system; Differential electrochemical mass spectrometry; Electrochemical reaction; Electrochemistry; Faradaic reaction; Mass spectrometry; Non-aqueous electrolyte; Volatile product
资金
- Federal Ministry of Education and Research of Germany (BMBF) [FKZ:03X4624C]
- DFG [SFB 624, SFB 813]
Differential electrochemical mass spectrometry (DEMS) has become an indispensable tool for not only qualitative and quantitative detection of volatile products or intermediates of continuous Faradaic reactions, but also determination of the amount of adsorbates (sub-layer or monolayer) at different electrode surfaces by means of their desorption. In the present review, we give a short introduction about the history of the combination of electrochemistry and MS (EC-MS), followed by a summary of the several types of DEMS cell that are applicable for different purposes. We present in detail the calibration of DEMS systems and their application in aqueous and non-aqueous electrolytes. (C) 2015 Elsevier B.V. All rights reserved.
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