期刊
ORGANOMETALLICS
卷 33, 期 4, 页码 994-1001出版社
AMER CHEMICAL SOC
DOI: 10.1021/om401158a
关键词
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资金
- National Natural Science Foundation of China [21174095, 21132002, 21372172]
- PAPD
- Qing Lan Project
Zirconium and titanium complexes 1 and 2, bearing an amine-bridged bis(phenolato) ligand, have been synthesized and characterized. Although 1 and 2 were inactive in catalyzing intermolecular hydroamination reactions, cationic complexes generated in situ from treatment of 1 and 2 with borate [Ph3C][B(C6F5)(4)], respectively, were found to be highly active. In general, excellent yields (up to > 99%) and 100% regioselectivity for a broad range of terminal alkynes and anilines were observed within a reaction time of 1 h. Reactions with internal alkynes of moderate sterics also led to good yields and moderate regioselectivity. A kinetic study was also conducted, which provided some insights into the mechanism of hydroamination reactions.
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