期刊
ORGANOMETALLICS
卷 33, 期 20, 页码 5708-5715出版社
AMER CHEMICAL SOC
DOI: 10.1021/om500506y
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资金
- EPFL
- Swiss National Science Foundation [200020_144393/1]
- Swiss National Science Foundation (SNF) [200020_144393] Funding Source: Swiss National Science Foundation (SNF)
The mechanism of alkylaryl Kumada coupling catalyzed by the nickel pincer complex Nickamine was studied. Experiments using radical-probe substrates and DFT calculations established a bimetallic oxidative addition mechanism. Kinetic measurements showed that transmetalation rather than oxidative addition was the turnover-determining step. The transmetalation involved a bimetallic pathway.
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