期刊
ORGANOMETALLICS
卷 32, 期 10, 页码 3108-3120出版社
AMER CHEMICAL SOC
DOI: 10.1021/om400310z
关键词
-
资金
- EPSRC
- GlaxoSmithKline
- Royal Society
- EPSRC [EP/D078776/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/D078776/1] Funding Source: researchfish
The effects of substituting (pseudo)halide for anionic imidate ligands in Au(I) and Au(III) (i.e. [AuBr(NHC)] and [AuBr3(NHC)]) complexes have been investigated. [Au(N-imidate)(NHC)] and [AuBr,(N-imidate)(NHC)] complexes were prepared and the structure and bonding of the complexes examined spectroscopically and crystallographically. The [AuBr2(N-imidate)(NHC)] complexes, in combination with Ag salts, were tested for catalytic activity in the cycloisomerization of 1,5-enynes and found to be more effective than the tribromide analogues (e.g. [AuBr3(NHC)]). Subtle changes to the anionic imidate ligand structure had a pronounced effect on the catalytic activity of the Au(III) complexes.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据