期刊
ORGANOMETALLICS
卷 32, 期 6, 页码 1575-1578出版社
AMER CHEMICAL SOC
DOI: 10.1021/om301246z
关键词
-
资金
- University of Victoria
- NSERC of Canada
Dehydrocoupling and hydrosilation reactions of the Si-H bonds in poly(phenylsilane) catalyzed by B(C6F5)(3) allow the preparation of new polymers containing both Si-H and Si-SR side chains. This postpolymerization modification takes place without any observable competing Si-Si bond cleavage, unlike other Lewis acid, transition-metal, or radical mediated routes. The -SR-functionalized polymers have been characterized by GPC, IR, UV-vis, elemental analysis, and H-1, C-13, and Si-29 NMR.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据