期刊
ORGANOMETALLICS
卷 32, 期 13, 页码 3769-3772出版社
AMER CHEMICAL SOC
DOI: 10.1021/om400402r
关键词
-
资金
- ERC
- EPSRC
- Sasol
Ammonia borane dehydrogenation can be catalyzed by a number of organometallic species. [Ir(kappa(2)-(IBu)-Bu-t)(2)][PF6] ((IBu)-Bu-t = 1,3-bis(tert-butyl)imidazol-2-ylidene) is the most active catalyst for this process that has been reported to date. We explore herein the absolute limits of the use of this and related complexes, including [Ir(kappa(2)-(IBu)-Bu-t)(2)][BAr4F], [Ir(H)(2)((IBu)-Bu-t)(2)]-[BAr4F], and [Ir(kappa(2)-(IBu)-Bu-t)(2)(NH3)][BAr4F] (BAr4F = tetrakis(3,5-bis(trifluoromethyl)phenyl)borate).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据