期刊
ORGANOMETALLICS
卷 31, 期 17, 页码 6420-6427出版社
AMER CHEMICAL SOC
DOI: 10.1021/om3006454
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资金
- Spanish Ministerio de Economia y Competitividad [CTQ2009-11457]
- University of Oviedo
- Spanish Ministerio de Economia y Competitividad (PGE) [CTQ2009-11457]
The reactivity of the mixed-ligand carbonyl isocyanide complexes fac-[Mn(CNR)(CO)(3)(bipy)](+) (la, R = Ph; 1b, R = xylyl; 1c, R = Me; 1d, R = CH2Ph; 1e, R = tBu) with the primary amines NH2Me and NH2CH2CH2CH2Br has been studied. Nucleophilic addition of the amine to a carbonyl ligand or to the isocyanide ligand may take place, depending on the nature of the amine, the substituent in the isocyanide ligand, and the reaction conditions; even replacement of a carbonyl ligand may occur. Thus, a variety of carbamoyl (2a-e), diaminocarbene (3a-d, 5a-d), N,O-heterocyclic carbene (6b), and amine (4b,c) complexes of manganese(I) has been obtained and characterized by spectroscopic and/or X-ray diffraction methods.
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