期刊
ORGANOMETALLICS
卷 30, 期 17, 页码 4539-4543出版社
AMER CHEMICAL SOC
DOI: 10.1021/om200248f
关键词
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资金
- Ministry of Education, Culture, Sports, Science and Technology of Japan [23550057]
- Tohoku University
- Grants-in-Aid for Scientific Research [23550057] Funding Source: KAKEN
When the Co-2(CO)(8)-catalyzed reaction of alkynes with thiols is conducted under the pressure of carbon monoxide, a novel thiolative lactonization with simultaneous introduction of two carbon monoxide molecules into the carbon carbon triple bonds takes place successfully to afford alpha,beta-unsaturated gamma-thio-gamma-lactones with excellent regioselectivity.
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