期刊
ORGANOMETALLICS
卷 30, 期 10, 页码 2640-2642出版社
AMER CHEMICAL SOC
DOI: 10.1021/om200197s
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资金
- IFP Energies
We report a novel iron (III)-based catalytic system formed by the addition of an anionic N,N,N ligand to an iron(Ill) precursor. The complex has been characterized by FT-IR, mass spectrometry, and X-ray diffraction. This precatalyst proved to form a stable, active species for the selective oligomerization of ethylene. Up to 66 wt % of butenes was obtained with a selectivity of 98% in 1-butene.
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