Article
Polymer Science
Yi Wan, Yun Bai, Hai Xu, Jianghua He, Yuetao Zhang
Summary: The study successfully synthesized five chiral binuclear aluminum methyl complexes, which catalyze the ring-opening polymerization of rac-lactide in a controlled manner and produce polymers with high isoselectivity. The kinetic studies show a first-order dependence on monomer concentration, supporting an enantiomorphic site control mechanism for the catalysts. This strategy can also be applied to other lactones for ring-opening polymerization.
MACROMOLECULAR RAPID COMMUNICATIONS
(2021)
Article
Chemistry, Inorganic & Nuclear
Marta Navarro, David Gonzalez-Lizana, Luis F. Sanchez-Barba, Andres Garces, Israel Fernandez, Agustin Lara-Sanchez, Ana M. Rodriguez
Summary: The successful design and preparation of novel helical heterobimetallic Al/Mg-based complexes as potential catalysts were described in this work. The complexes showed high efficiency and were characterized by single-crystal X-ray analysis. They were found to exhibit a rearrangement in solution and demonstrated utility and high selectivity as catalysts in the ring-opening polymerization of l- and rac-lactide.
INORGANIC CHEMISTRY
(2023)
Article
Polymer Science
Zhedong Li, Shiwei Duan, Na Zhao, Zhibo Li
Summary: In this study, two bulky phenyl diphosphazene bases, p-PDPB and m-PDPB, were synthesized and used in combination with ureas and squaramides as hydrogen-bond donors to mediate stereocontrolled ring opening polymerization (ROP) of lactide. The phenyl diphosphazene based/urea binary catalytic system successfully synthesized semicrystalline PLAs with narrow dispersity and high tacticity (P-m up to 0.84) in a well-controlled manner. Structural analysis confirmed the linear structure and high end-group fidelity of the resulting polymers, and MALDI-TOF MS analysis indicated the good controllability of the binary catalytic system with minimal transesterification.
JOURNAL OF POLYMER SCIENCE
(2023)
Article
Chemistry, Organic
Yali Zhou, Gary S. Nichol, Jennifer A. Garden
Summary: Experimental results show that the polymerization activity of lithium complexes is closely related to their aggregation states, with catalysts in low aggregation states exhibiting higher propagation rates due to improved metal accessibility and kinetic mobility. The nature of the ligand substituents and solvent can influence the aggregation of the catalyst in both solid and solution states.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
(2021)
Article
Biochemistry & Molecular Biology
Kirill V. Zaitsev, Andrey D. Trubachev, Yuri F. Oprunenko, Yuliya A. Piskun, Irina V. Vasilenko, Andrei V. Churakov, Sergei V. Kostjuk
Summary: A highly efficient one-step approach to macromonomer synthesis using modified aluminum complexes as catalysts was developed. Aluminum salen complexes functionalized with unsaturated alcohol were synthesized and their structures and catalytic activities were studied. Among the complexes, 3b exhibited the highest activity in ROP, producing polyesters with controlled molecular weights and high number-average functionalities.
Article
Chemistry, Inorganic & Nuclear
Valentin Vaillant-Coindard, Florian Chotard, Benjamin Theron, Cedric Balan, Jerome Bayardon, Raluca Malacea-Kabbara, Ewen Bodio, Yoann Rousselin, Paul Fleurat-Lessard, Pierre Le Gendre
Summary: Ethylene- and phenylene-bridged bis-(salicylamidine) ligands can be easily synthesized from ethylene or phenylenediamine and iminium chloride derivatives. These complexes show catalytic activity in the controlled ring-opening polymerization of rac-lactide to generate poly(lactic acid) with slight isotactic bias.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Physical
Sami Gesslbauer, George Hutchinson, Andrew J. P. White, Jordi Bures, Charles Romain
Summary: The research demonstrates that the activity of chiral-at-metal aluminum complexes in cyclic ester ring-opening polymerization is influenced by the alkoxide bulkiness and complex chirality. Experimental results show that using enantiopure catalysts can achieve better results than using a mixture of racemic catalysts.
Review
Chemistry, Multidisciplinary
Mathieu J. -L. Tschan, Regis M. Gauvin, Christophe M. Thomas
Summary: This review summarizes the recent developments in biodegradable polymeric materials over the past decade, with a focus on the stereoselective ring-opening polymerization of cyclic esters and the emergence of metal-free stereocontrolled ROP technology. The study emphasizes the synthesis of new stereoselective polymerization catalysts and chiral monomers, while also highlighting the quantification and mechanisms of stereocontrol.
CHEMICAL SOCIETY REVIEWS
(2021)
Article
Chemistry, Physical
Theo A. Rusmore, Michael J. Behlen, Alex John, Daniel T. Glatzhofer, Kenneth M. Nicholas
Summary: In this study, chiral diimine-salen molybdenum complexes were evaluated for their potential as catalysts for oxidative kinetic resolution reactions. It was found that certain catalysts exhibited activity for the oxidation of racemic monophosphines, but with low to moderate enantioselectivities. Key structure/reactivity features of the catalysts include the presence of a p-NO2 substituent on the salen-unit increasing catalyst activity, and increasing steric bulk of the ortho-salen-substituent increasing enantioselectivity.
MOLECULAR CATALYSIS
(2021)
Article
Chemistry, Physical
Hui Sun, Huijian Shang, Bin Cui
Summary: Asymmetric catalysis using a chiral (Salen)Mn(III) complex has been successfully applied to highly enantioselective intramolecular haloamination reactions of alkenes. Experimental results suggest that the polarization of the C5-C6 bond has a significant effect on the regioselectivity of the products.
Article
Polymer Science
Salvatore Impemba, Gabriele Manca, Irene Tozio, Stefano Milione
Summary: In this study, new zinc catalysts were developed using thioether-amide ligands for the ring-opening polymerization of cyclic esters. Experimental and theoretical studies provided insights into the parameters that influence catalytic activity. The catalysts exhibited high activity in the polymerization of rac-beta-butyrolactone and showed agreement with expected results in terms of molecular weight and polydispersity index.
Article
Chemistry, Inorganic & Nuclear
Zoe R. Turner, Jessica V. Lamb, Thomas P. Robinson, Dipa Mandal, Jean-Charles Buffet, Dermot O'Hare
Summary: In this study, a new family of group 4 permethylpentalene aryloxide and alkoxide complexes were synthesised and fully characterised by multinuclear NMR spectroscopy and single-crystal X-ray diffraction. Initiators 3 was found to exhibit the highest activity for the ring-opening polymerisation of l-lactide.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Inorganic & Nuclear
Dong Xia, Hehua Li, Tang Li, Haiyan Ma
Summary: A new family of magnesium complexes supported by tetradentate aminophenolate ligands act as effective initiators for the ROP of rac-lactide, producing PLAs with moderate isotacticities. The formation of isotactic PLAs with dominant stereoblock sequences was witnessed, and the inequivalent coordination of two pyridyl pendant arms in these magnesium complexes might be the source of exerting isoselective control.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Physical
Weronika Gruszka, Haopeng Sha, Antoine Buchard, Jennifer A. Garden
Summary: The study reports the first heterobimetallic LA ROP catalysts featuring only divalent metals, with Mg/Zn and Ca/Zn complexes showing high activity in LA and ε-CL ROP, and the Ca/Zn complex exhibiting the highest activity. The enhanced activity is attributed to Lewis acidic metals enhancing monomer coordination.
CATALYSIS SCIENCE & TECHNOLOGY
(2022)
Article
Chemistry, Multidisciplinary
Mohamed Samir Zaky, Anne-Laure Wirotius, Olivier Coulembier, Gilles Guichard, Daniel Taton
Summary: The stereoselective ring-opening polymerization of racemic lactide was achieved using Takemoto's catalyst and a phosphazene base, resulting in highly isotactic, semi-crystalline, and metal-free polylactide.
CHEMICAL COMMUNICATIONS
(2021)
Article
Chemistry, Inorganic & Nuclear
Kavindu Dilshan Kariyawasam Pathirana, Pokhraj Ghosh, Chung-H Hsieh, Lindy Chase Elrod, Nattamai Bhuvanesh, Donald J. Darensbourg, Marcetta Y. Darensbourg
INORGANIC CHEMISTRY
(2020)
Article
Chemistry, Inorganic & Nuclear
Gulzar A. Bhat, Ahmed Z. Rashad, Tucker M. Folsom, Donald J. Darensbourg
Article
Chemistry, Multidisciplinary
Tian-Jun Yue, Gulzar A. Bhat, Wen-Jian Zhang, Wei-Min Ren, Xiao-Bing Lu, Donald J. Darensbourg
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2020)
Article
Polymer Science
Gulzar A. Bhat, Marcetta Y. Darensbourg, Donald J. Darensbourg
Summary: The synthesis of poly(propylene carbonate) with 100% C-13-labeled carbonate carbons has been reported, where the nu(CO3) vibration is lowered by 45 cm(-1), allowing for the observation of nu(NO) stretching motions in incorporated dinitrosyl iron complexes.
Article
Chemistry, Multidisciplinary
Tian-Jun Yue, Bai-Hao Ren, Wen-Jian Zhang, Xiao-Bing Lu, Wei-Min Ren, Donald J. Darensbourg
Summary: A synthetic strategy was presented for enhancing the optical properties of CO2-based polycarbonates by modifying the polymer's topological structure, resulting in terpolymers with tunable carbonate linkages and improved optical properties. This approach offers a promising method for developing polymeric materials with enhanced optical properties while maintaining thermal stability.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Gulzar A. Bhat, Ahmed Z. Rashad, Xiaozhou Ji, Manuel Quiroz, Lei Fang, Donald J. Darensbourg
Summary: In this study, TEMPO-appended polymonothiocarbonates were synthesized through ring-opening copolymerization under ambient conditions. Both atactic and isotactic versions of the polymer were prepared, with the isotactic form showing significantly higher conductivity attributed to its well-defined stereochemistry and regulated charge transport pathway compared to the atactic counterpart.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Mani Sengoden, Gulzar A. Bhat, Donald J. Darensbourg
Summary: Polymers obtained from renewable monomers have attracted attention for their ability to address environmental issues and depletion of fossil fuels. In this study, a renewable eugenol-based epoxide was synthesized and its reactions with CO2, COS, and CS2 were examined. It was found that eugenol epoxide preferentially formed cyclic products with CO2 and CS2, while reacting with COS resulted in the regioselective formation of polymonothiocarbonate polymers at room temperature. The molecular structures of the renewable monomers and their cyclic products were determined using single crystal X-ray diffraction studies. Thermal gravimetric analysis and differential scanning calorimetry revealed that the polymonothiocarbonate polymers were stable up to 200 degrees C and had high glass transition temperatures.
Article
Chemistry, Inorganic & Nuclear
Zachary M. Martinez, Tucker M. Folsom, Yicheng Tong, Ashley K. Archambeau, Donald J. Darensbourg, Michael B. Hall, Cynthia B. Powell, Gregory L. Powell
Summary: The mechanism of CO substitution reaction involving diosmium carbonyl sawhorse complex was studied experimentally and theoretically, revealing a dissociative interchange mechanism. Kinetic measurements and stability studies were in agreement with each other, explaining the unexpected combination of kinetics and stability characteristics observed in the reaction.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Fang-Yu Ren, Kaihong Chen, Li-Qi Qiu, Jin-Mei Chen, Donald J. Darensbourg, Liang-Nian He
Summary: A triblock amphiphilic polymer derived from the copolymerization of CO2 and epoxides is able to efficiently catalyze the visible-light-driven reduction of CO2 to CO. The polymer forms spherical micelles in water, where the metal catalyst is sequestered. The amphiphilic polycarbonate micelle rhenium catalyst shows enhanced catalytic activity and selectivity compared to the corresponding molecular rhenium catalyst in organic solvent, while also suppressing the generation of H-2.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Multidisciplinary
Peiran Wei, Gulzar A. Bhat, Ciera E. Cipriani, Hamza Mohammad, Krista Schoonover, Emily B. Pentzer, Donald J. Darensbourg
Summary: This study reports on the facile synthesis and 3D printing of triblock copolymers that can be covalently modified. Thixotropic inks suitable for direct ink write printing were formulated by dissolving the block copolymers in organic solvent and dispersing NaCl particles. Printed structures with surfaces that could be modified and objects with high solvent resistance and selective degradability were achieved.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Polymer Science
Mani Sengoden, Gulzar A. Bhat, Donald J. Darensbourg
Summary: In recent years, chemists worldwide have made significant progress in synthesizing sustainable polymers from natural product-based building blocks. This shift is driven by the environmental impact of non-biodegradable oil-based polymers and the need to utilize renewable feedstocks. This study presents the synthesis of novel terpolymer using a well-defined catalyst system and investigates the mechanistic details of the polymerization reactions. The resulting terpolymers show increased thermal stability with higher proportions of the renewable building block.
Review
Chemistry, Multidisciplinary
Peiran Wei, Gulzar A. Bhat, Donald J. Darensbourg
Summary: This paper presents a concise review of recent progress in processing techniques for aliphatic polycarbonates, including controlled self-assembly, electrospinning, additive manufacturing, and others. The aim is to provide researchers with an enriched toolbox for selecting the most suitable technique for their materials.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Mani Sengoden, Gulzar A. Bhat, Donald J. Darensbourg
Summary: Recent years have seen significant research efforts in the development of metal-free organocatalysts for coupling reactions of CO2 and epoxides. In this study, a series of boron-phosphonium organocatalysts were synthesized and characterized for catalyzing these reactions. The catalysts exhibited high selectivity and were found to be less hygroscopic compared to metal-based catalysts. They successfully facilitated the copolymerization of CO2 and epoxides to form polycarbonates.
Review
Chemistry, Multidisciplinary
Gulzar A. Bhat, Donald J. Darensbourg
Summary: Sustainability requires the reuse of carbon sources from CO2 emissions, making carbon capture and utilization essential. Coupling of oxiranes (epoxides) with CO2 can generate cyclic carbonates and polymeric materials, providing a potential solution. It is important to use epoxides derived from renewable resources for a sustainable process.
Article
Polymer Science
David K. Tran, Ahmed Z. Rashad, Donald J. Darensbourg, Karen L. Wooley
Summary: The synthetic transformation of d-xylose into a four-membered cyclic ether enables reactions with carbon dioxide to produce linear polycarbonates through either one-step ring-opening copolymerisation (ROCOP) directly or sequential isolation of a preformed six-membered cyclic carbonate followed by ring-opening polymerisation (ROP).