期刊
ORGANOMETALLICS
卷 29, 期 20, 页码 4424-4427出版社
AMER CHEMICAL SOC
DOI: 10.1021/om100789n
关键词
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资金
- Alfred Werner Foundation
- ETH Zurich
The synthesis of a novel fluorinated Au(I) N-heterocyclic carbene is disclosed together with solid-state and solution-phase conformational analysis. The potential of the fluorine gauche effect [sigma(C-H) --> sigma(C-F)*] for controlling the topology of catalytically relevant architectures is showcased by a representative NHC in which the C-F bond is beta to the triazolium moiety.
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