期刊
ORGANOMETALLICS
卷 29, 期 20, 页码 4579-4583出版社
AMER CHEMICAL SOC
DOI: 10.1021/om1007049
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资金
- EPSRC
- ERC
- Engineering and Physical Sciences Research Council [EP/H015418/1] Funding Source: researchfish
- EPSRC [EP/H015418/1] Funding Source: UKRI
The relative L-Au bond dissociation enthalpies of [Au(L)Cl] (L = tetrahydrothiophene (tht), PCynPh(3-n), [1,1'-bipheny1]-2-yldicyclohexylphosphine (Cy-JohnPhos), dicyclohexyl(2',6'-dimethoxy[1,1'-biphenyl]-2-yl)phosphine (SPhos), dicyclohexyl[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine (XPhos), P(OPh)(3), P(O-2,4-(Bu2Ph)-Bu-t)(3), P((OPr)-Pr-i)(3), and the two enantiomers of 1,1', 1 ''-[phosphinidynetris[oxy-(1-S/R)-[1,1'-binaphthalene]-2',2-diyl]] tricyclo[3.3113,7]decane-1-carboxylic acid ester) are examined, These enthalpic values are examined in terms of the intrinsic steric and electronic properties of the ancillary ligand. Estimates of the absolute BDE for the investigated ligands are presented.
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