期刊
ORGANOMETALLICS
卷 29, 期 21, 页码 4762-4765出版社
AMER CHEMICAL SOC
DOI: 10.1021/om1005337
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资金
- EPSRC [EP/G006156/1]
- EPSRC [EP/G006156/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/G006156/1] Funding Source: researchfish
The syntheses and structural characterization of sterically encumbered 1,2-diborylferrocenes are reported, together with an investigation of their anion recognition capabilities with respect to fluoride and cyanide. Surprisingly, 1,2-fc(BMes(2))(2) is found to be highly selective for CN-, with the uptake of F- being shown to be not only thermodynamically less favorable but also kinetically much slower.
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