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Selective Platinum-Catalyzed C-F Bond Activation as a Route to Fluorinated Aryl Methyl Ethers

ORGANOMETALLICS (2009)

期刊

ORGANOMETALLICS

卷 28, 期 8, 页码 2356-2359

出版社

AMER CHEMICAL SOC

DOI: 10.1021/om900100f

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类别

Chemistry, Inorganic & Nuclear Chemistry, Organic

资金

University of British Columbia
NSERC
Merck Frosst
Canada Foundation for Innovation
British Columbia Knowledge Fund

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Protocol

Reagent

摘要

[(CH3)(2)Pt(mu-SMe2)](2)catalyzes the formation of aryl methyl ethers via selective C-F bond activation of polyfluoroarylimines. This reaction is functional group tolerant and proceeds in good to excellent yields. The optimization and preliminary substrate scope of this process are described.

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