期刊
ORGANOMETALLICS
卷 28, 期 14, 页码 3981-3989出版社
AMER CHEMICAL SOC
DOI: 10.1021/om801029k
关键词
-
资金
- Research Grants Council of the HKSAR, China
Rh(ttp)Cl (1a) (ttp = 5,10,15,20-tetrakistolylporphyinato dianion) was found to react with methanol at a high temperature of 150 degrees C in the presence of inorganic bases to give a high yield of Rh(ttp)CH3 (2a), up to 87%. Rh(ttp)H (1d) is suggested to be the key intermediate for the carbon-oxygen bond cleavage.
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