期刊
ORGANOMETALLICS
卷 27, 期 21, 页码 5571-5576出版社
AMER CHEMICAL SOC
DOI: 10.1021/om800442a
关键词
-
资金
- Hungarian Scientific Research Foundation [OTKA T048796]
The thermodynamic and kinetic stability of bis(diisopropylamino)cyclopropenylidene and related molecules were investigated by quantum chemical methods. The main stabilizing factor in the amino-substituted cyclopropenylidene is the significant pi-electron shift from the amino substituents, via a nonaromatic ylidic structure; however, its successful synthesis is based on its high kinetic stability. The silicon and germanium analogues show lower stabilization than the synthesized carbene. However, when investigating their reactions, we found that both amino-disubstituted three-membered silylene and germylene have considerable kinetic stability.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据