期刊
ORGANOMETALLICS
卷 27, 期 22, 页码 5737-5740出版社
AMER CHEMICAL SOC
DOI: 10.1021/om8009365
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资金
- Moore Foundation
- BP
Iridium complexes supported by the PNP amidophosphine scaffold (PNP = [N(2-(PPr2)-Pr-i-4-Me-C6H3)(2)](-)) perform the selective double C-H activation of methyl amines to produce iridium(III) dihydrido aminocarbenes. The reactivity of these complexes is presented and contrasted with that observed for the previously reported iridium(I) alkoxycarbenes.
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