Article
Chemistry, Organic
Yuta Kudoh, Kaori Fujii, Yoshifumi Kimura, Mao Minoura, Yoshihiro Matano
Summary: In this study, 1,2,5,10-tetraphenylanthra[2,3-b]phosphole oxides and 1-methyl-1,2,5,10-tetraphenylanthra[2,3-b]phospholium salts were prepared and their optical properties were investigated. The results showed that the substituent at the para position and the fused anthracene moiety significantly affected the fluorescence properties of the P-bridged 2-styrylanthracene skeleton.
JOURNAL OF ORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Liuzhong Yuan, Yujia Liu, Wenting Sun, Kaiqi Ye, Chuandong Dou, Yue Wang
Summary: Incorporation of heteroatoms into polyarenes has been proven to be an effective method to modify their structures and properties. In this study, P=O-containing dibenzopentaarene isomers (5a and 5b) were designed and synthesized, and their structures and properties were investigated alongside dibenzopentaarenes containing Si and B heterocycles (3 and 4). The incorporation of heterocycles greatly influenced the molecular and packing structures, as well as the electronic structures and properties of the polyarenes.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Inorganic & Nuclear
Xiao-Chen Ren, Jun Li, Wen-Hao Wang, Ya-Nan Shao, Bo Zhang, Lian-Zhi Li
Summary: Three new heterometallic silver-based haloplumbate hybrids, characterized by narrow optical band gaps and rapid photoelectrical switching properties, were successfully synthesized and characterized by solvothermal methods in this study.
JOURNAL OF SOLID STATE CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Li-Zhi Han, Cheng-Qi Jiao, Wei-Chao Chen, Kui-Zhan Shao, Long-Yi Jin, Zhong-Min Su
Summary: Two novel tetra-nuclear Yb-III-incorporated selenotungstate clusters were isolated through pH-controlled assembly, showing the first Yb-III-containing polyoxotungstates with selenium heteroatoms. Compound 1 exhibited field-induced single-molecule magnetic behavior, while compound 2 displayed antiferromagnetic interactions between ytterbium centers.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Inorganic & Nuclear
Yana M. Dikova, Dmitry S. Yufit, J. A. Gareth Williams
Summary: Platinum(II) complexes of NNC-cyclometalating ligands based on 6-phenyl-2,2 '-bipyridine (HL1) have been extensively studied for their luminescence properties. Oxidation of PtL1Cl and its analogues with differently substituted aryl rings, PtL2-6Cl, by chlorine and/or iodobenzene dichloride generates Pt(IV) compounds of the form Pt(NNC-Ln)Cl3 (n = 1-6). These PtLnCl3 compounds react with 2-arylpyridines to form a new class of Pt(IV) complexes [Pt(NNC)(NC)Cl]+. The UV-vis absorption spectra and phosphorescence properties of these complexes are affected by the electron richness of the aryl ring.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Organic
Daisuke Furusho, Naoki Shida, Ryoyu Hifumi, Ikuyoshi Tomita, Shinsuke Inagi
Summary: In this study, the optoelectronic properties of distyrylbenzene derivatives with substituents on the vinylene moieties were investigated. The obtained compounds were characterized using UV-vis and fluorescence spectroscopy, and their crystal structures were determined by single crystal X-ray diffraction and Hirshfeld surface analysis to understand the intermolecular contacts.
JOURNAL OF ORGANIC CHEMISTRY
(2023)
Article
Polymer Science
Zhijian Zhang, Kai Yang, Jianying Li, Zhenghong Jing, Yawei Qin, Jin-Yong Dong
Summary: The use of omega-alkenylmethyldichlorosilane as a long-chain-branching agent in the fully implemented impact copolymerization of propylene has shown significant improvements in IPCs. The introduction of LCB structures has led to advancements in melt properties, phase morphology, melt crystallization, and mechanical properties of the copolymer, resulting in enhanced stiffness and toughness.
Article
Chemistry, Multidisciplinary
Shunki Ikeda, Aya Yoshimura, Takashi Shirahata, Yoshihiro Matano, Yohji Misaki
Summary: Three new pi-conjugated molecules containing a TTF unit and a benzo[b]phosphole oxide unit were successfully synthesized. X-ray structural analysis showed high planarity of the benzo[b]phosphole oxide unit and a bending structure of the TTF unit. Cyclic voltammetry revealed two pairs of redox waves from the TTF site.
Article
Chemistry, Physical
Maryam Fashandi, Solmaz Karamikamkar, Siu. N. Leung, Hani E. Naguib, Jiang Hong, Bingqing Liang, Chul B. Park
Summary: ATMS is commonly used as a silane coupling agent and can be incorporated into aerogels with the help of PVTMS for improved properties. The use of acid and base catalysts further enhances the performance of the aerogels. Characterization methods confirm the excellent physical and chemical properties of ATMS:PVTMS aerogels.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Optics
Yifeng Shi, Gerile Naren, Ying Zhang, Jiakang Han, Aorigele Bohnuud
Summary: This study prepared three new neodymium (III) complexes, investigated their chemical and physical properties, and found that they have excellent optical and luminescent properties.
OPTICS AND LASER TECHNOLOGY
(2022)
Review
Biochemistry & Molecular Biology
Evgeny M. Kopnin
Summary: The high-pressure synthesis and crystal structures of the homologous series AuBa2(Ca,Ln)(n-1)CunO2n+3 (n = 1-4; Ln = rare-earth cations) are described in detail and compared with the corresponding members of the Hg-homologous series. Various cuprates containing flat structural fragments synthesized mainly at high pressure are compared in terms of structural peculiarities and superconducting properties. The importance and future prospects of high-pressure application for the preparation of new superconducting oxides are discussed.
Article
Chemistry, Physical
Wooseok Ki, Xiuze Hei, Hee Taek Yi, Wei Liu, Simon J. Teat, Mengjun Li, Yang Fang, Vitaly Podzorov, Eric Garfunkel, Jing Li
Summary: A group of copper iodide-based hybrid semiconductors with tunable photoluminescence and high charge carrier mobility has been synthesized and characterized, showing promising potential as a new type of emissive layer for LED devices.
CHEMISTRY OF MATERIALS
(2021)
Article
Chemistry, Analytical
Ying Yang, Qian Lei, Jun Li, Cheng Hong, Zhenting Zhao, Hongyan Xu, Jie Hu
Summary: The electrochemical nitrite sensor based on gold nanoparticles modified molybdenum disulfide and reduced graphene oxide shows excellent performance in terms of high sensitivity, short response time, low detection limit, and good linear detection range. The synergistic effect between MoS2 and rGO nanosheets, along with the catalytic property of appropriate content of Au nanoparticles, contributes to the outstanding electrochemical performances of the sensor.
MICROCHEMICAL JOURNAL
(2022)
Article
Chemistry, Inorganic & Nuclear
Kelsey R. Cairns, William Levason, Gillian Reid, Wenjian Zhang
Summary: The reaction of Group 13 triflates with various ligands results in the formation of diverse complexes, some of which have unique structures as confirmed by crystallography analysis, highlighting the coordination environment of the ligands with the metal ions.
Article
Chemistry, Inorganic & Nuclear
Neskarlys Rios, Franmerly Fuentes, Deivi Oliveros, Jose R. Mora, Juan M. Garcia-Garfido, Yomaira Otero
Summary: A new phosphole derivative was synthesized with high yield, along with the synthesis of two new copper-phosphole complexes. The compounds were characterized by various techniques and their photophysical properties were analyzed.
JOURNAL OF COORDINATION CHEMISTRY
(2021)
Article
Chemistry, Physical
Tomokazu Umeyama, Han Xu, Tomoya Ohara, Yusuke Tsutsui, Shu Seki, Hiroshi Imahori
Summary: Bismuthene, a two-dimensional material obtained from bulk bismuth, was successfully prepared and applied onto a semiconducting SnO2 electrode, demonstrating an increase in conductivity upon photoexcitation. Furthermore, the hybrid composite of FLBi and C-60 showed photoinduced energy transfer without producing the charge-separated state, showing potential for constructing optoelectronic devices.
JOURNAL OF PHYSICAL CHEMISTRY C
(2021)
Article
Chemistry, Physical
Bhagyashree Mahesha Sachith, Takuya Okamoto, Sushant Ghimire, Tomokazu Umeyama, Yuta Takano, Hiroshi Imahori, Vasudevanpillai Biju
Summary: This study reveals the distance-dependent and diffusion-controlled interfacial electron transfer across perovskite-electron acceptor heterojunction films. Perovskite nanocrystals exhibit long-range carrier migration in self-assembled films, while acceptors quench photoluminescence intensity without affecting lifetime. The research underscores the importance of interfacial electron transfer in perovskite films.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2021)
Article
Chemistry, Multidisciplinary
Sharvan Kumar, Kohshi Yoshida, Yusuke Hattori, Tomohiro Higashino, Hiroshi Imahori, Shu Seki
Summary: This study reports a strategic methodology for isolation of stable negatively charged organic compounds and provides detailed descriptions of the structures and properties of two mysterious compounds. These compounds exhibit high stability under ambient conditions due to their high delocalization, and can be purified by column chromatography.
Article
Chemistry, Multidisciplinary
Qi Guo, Tomohiro Higashino, Kosaku Kato, Akira Yamakata, Hiroshi Imahori
Summary: Donor-pi-acceptor type porphyrin-fullerene dyads with an acetylene bridge were designed and synthesized. The dyad was found to produce a stable charge-separated state in benzonitrile. Compared to the porphyrin reference without the fullerene moiety, the p-type dye-sensitized solar cells with the dyad exhibited higher photovoltaic performance.
Article
Nanoscience & Nanotechnology
Sharvan Kumar, Yun Hee Koo, Tomohiro Higashino, Wakana Matsuda, Samrat Ghosh, Yusuke Tsutsui, Masayuki Suda, Hiroshi Imahori, Katsuaki Suzuki, Hironori Kaji, Shu Seki
Summary: The preparation and characterization of a new class of electron deficient organic compounds, truxenone triimide (TTI), is reported. The electrochemical analysis confirms that multi-imidization helps in lowering the LUMO energy level, resulting in improved optoelectronic and/or semiconducting properties. The charge carrier transport properties and dynamics of the compounds are studied using flash-photolysis time-resolved microwave conductivity measurements. Compound 2D exhibits a high electron mobility of 0.27 cm(2) V-1 s(-1) under ambient conditions.
ADVANCED ELECTRONIC MATERIALS
(2022)
Article
Chemistry, Physical
Tomohiro Higashino, Hiroshi Imahori
Summary: Redox shuttles are crucial in the performance of DSSCs. Copper(I/II) complexes have emerged as third-generation redox shuttles and achieved up to 13% power conversion efficiency due to their more positive redox potentials.
ACS ENERGY LETTERS
(2022)
Article
Chemistry, Multidisciplinary
Tomohiro Higashino, Rikiya Iizumi, Hiroshi Imahori
Summary: A rational synthetic approach for benzoheterole-fused porphyrins was developed and applied to the synthesis of benzothiophene- and indole-fused porphyrins. The resulting fused porphyrins exhibited red-shifted absorption and fluorescence, attributed to effective pi-expansion through heterole-fused structures. Furthermore, the pi-circuit of the indole-fused porphyrin could be controlled by a central metal ion.
Article
Polymer Science
Shaoxian Li, Ryosuke Nishikubo, Tatsuho Wada, Tomokazu Umeyama, Hiroshi Imahori, Akinori Saeki
Summary: This study evaluates the charge carrier dynamics in different structured organic solar cells and reveals the factors limiting the power conversion efficiency (PCE). The results show that the OSC with the highest PCE has low electron and hole mobilities, while the one with higher electron and hole mobilities has a lower PCE. Additionally, the OSC with the highest PCE exhibits the smallest bimolecular recombination coefficient.
Article
Chemistry, Multidisciplinary
Tomohiro Higashino, Kenichi Sugiura, Keigo Namikawa, Hiroshi Imahori
Summary: Trifluoromethyl groups were introduced into a push-pull-type porphyrin dye to modulate its energy levels and improve light-harvesting ability. The introduction of trifluoromethyl groups effectively lowered the excited-state oxidation potential of the dye. However, DSSCs using the dye with trifluoromethyl groups exhibited a lower power conversion efficiency due to aggregation tendencies.
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
(2023)
Review
Chemistry, Multidisciplinary
Hiroshi Imahori
Summary: We have designed and synthesized donor-acceptor linked systems to investigate the process of photo-induced charge separation. Porphyrin-fullerene and polymer-fullerene linked molecules have been found to be effective model systems for studying issues in excited-state generation, charge separation, and charge dissociation. We have also proposed a new concept, dynamic exciton, to establish a comprehensive photochemistry involving the manipulation of locally excited state, charge-transfer state, and charge-separated state. Moreover, we have developed versatile dyes and donor/acceptor molecules for better understanding the underlying mechanism and improving the performance of dye-sensitized solar cells and bulk heterojunction organic solar cells. Additionally, we have successfully utilized the giant dipole moment produced from donor-acceptor linked molecules to regulate the membrane potential of living biological cells, which is a promising approach in optogenetics and neuronal therapy by light.
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
(2023)
Article
Chemistry, Multidisciplinary
Qi Guo, Behnam Ghalei, Detao Qin, Daizu Mizutani, Ikumi Joko, Habib Al-Aziz, Tomohiro Higashino, Masateru M. Ito, Hiroshi Imahori, Easan Sivaniah
Summary: Graphene oxide (GO) serves as a promising platform for gas separation membranes. By introducing positively charged fullerene C-60 derivatives onto GO sheets, the interlayer spacing can be adjusted, resulting in enhanced gas separation efficiency.
CHEMICAL COMMUNICATIONS
(2023)
Review
Chemistry, Physical
Yuzhe Zhang, Tomohiro Higashino, Hiroshi Imahori
Summary: In recent decades, significant efforts have been devoted to developing porphyrin sensitizers for dye-sensitized solar cells (DSSCs) due to their advantages of easy fabrication, low-cost production, and relatively high power conversion efficiency (PCE). Certain molecular design principles and synthetic strategies have been proven effective in constructing high-performance porphyrin-based DSSCs. This review emphasizes the promising and effective synthetic strategies for rational design of porphyrins as sensitizers and highlights the key factors that greatly influence the photovoltaic performance, providing insightful perspectives on the correlation between molecular structure and photovoltaic performance.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Proceedings Paper
Engineering, Electrical & Electronic
Hiroshi Imahori
Summary: Dye-sensitized solar cells and bulk heterojunction organic photovoltaics have gained attention for their cost-effective potential in photovoltaic applications. Rational molecular engineering of organic materials in the photoactive layers can modulate their fundamental properties, meeting the requirements for high-performance organic photovoltaics. This article highlights recent representative examples developed by our team.
TWENTY-NINETH INTERNATIONAL WORKSHOP ON ACTIVE-MATRIX FLATPANEL DISPLAYS AND DEVICES: TFT TECHNOLOGIES AND FPD MATERIALS (AM-FPD 22)
(2022)
Review
Engineering, Electrical & Electronic
Lorenzo Vallan, Hiroshi Imahori
Summary: Carbon dots (CDs) are a broad term encompassing various organic materials obtained from different reagents and synthetic routes. The previously held belief that the fluorescence emission of CDs is attributed to large aromatic structures has been significantly downsized due to recent studies. Researchers have found that the chemical and emissive nature of CDs is specific to the combination of synthetic precursors used, and these systems also comprise nanoparticles, single molecules, oligomers, and aggregates with unique fluorescent behavior. This review is divided into two parts, discussing the structural and optical properties of different types of citric acid-based CDs as a benchmarking class, and their applications in energy conversion.
ACS APPLIED ELECTRONIC MATERIALS
(2022)
Article
Chemistry, Physical
Tomokazu Umeyama, Kensho Igarashi, Yasunari Tamai, Tatsuho Wada, Taiki Takeyama, Daiki Sasada, Keiichi Ishida, Tomoyuki Koganezawa, Shunsuke Ohtani, Kazuo Tanaka, Hideo Ohkita, Hiroshi Imahori
Summary: The comprehensive study on the relationship between the structure and the photophysical and photovoltaic properties of acceptor-donor-acceptor (A-D-A) type nonfullerene acceptors (NFAs) is crucial for design guidelines in high-performance organic photovoltaics (OPVs). The inclusion of naphthalene-cored D units in A-D-A type NFAs shows potential for achieving a long singlet exciton lifetime and resulting in high power conversion efficiency in NFA-based OPVs.
SUSTAINABLE ENERGY & FUELS
(2021)