4.6 Article

New Stable Catalytic Electrodes Functionalized with TEMPO for the Waste-Free Oxidation of Alcohol

期刊

ORGANIC PROCESS RESEARCH & DEVELOPMENT
卷 22, 期 9, 页码 1298-1305

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acs.oprd.8b00156

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alcohol oxidation; electrocatalytic activity; EASA; TEMPO; hydrophobicity; thin films

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We report the first catalytically active and stable sol-gel electrode functionalized with the TEMPO moiety for the highly selective oxidation of alcohols with an electric current only. The method shows broad applicability to different substrates, opening the route to the widespread adoption of this eminently clean technology by the fine chemical and pharmaceutical industries.

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