期刊
ORGANIC LETTERS
卷 20, 期 17, 页码 5448-5451出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b02325
关键词
-
资金
- Japan Society for the Promotion of Science [17K05794]
- Grants-in-Aid for Scientific Research [17K05794] Funding Source: KAKEN
We have achieved the nickel-catalyzed asymmetric propargylic amination of propargylic carbonates bearing an internal alkyne group. A wide variety of propargylic carbonates and N-methylaniline derivatives were tolerated under the reaction conditions, providing the corresponding chiral propargylic amines in up to 97% yield with up to 97% ee.
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