期刊
ORGANIC LETTERS
卷 16, 期 24, 页码 6342-6345出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol503111h
关键词
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资金
- 973 Program [2012CB215306]
- FRFCU [WK2060190025, WK2060190033, WK2060190029]
- NSFC [21325208, 21172209, 21272050, 21302178]
- CAS [KJCX2-EW-J02]
- SRFDP [20123402130008]
The first copper-catalyzed/promoted sp(3)-C SuzukiMiyaura coupling reaction of gem-diborylalkanes with nonactivated electrophilic reagents is reported. Not only 1, 1-diborylalkanes but also some other gem-diborylalkanes can be coupled with nonactivated primary alkyl halides, offering a new method for sp(3)Csp(3)C bond formation and, simultaneously, providing a new strategy for the synthesis of alkylboronic esters.
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