期刊
ORGANIC LETTERS
卷 16, 期 21, 页码 5744-5747出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol502808u
关键词
-
资金
- National Basic Research Program of China [2012CB821600]
- National Natural Science Foundation of China (NSFC) [21390400, 21172112, 21172118]
- Ministry of Education (MoE) [20131080083]
- Tsinghua University
Equilibrium acidities (pK(a)) of 14 aromatic thiols in four pure room temperature ionic liquids (RTILs) were precisely determined and the corresponding acidity scales were established for the first time. Regression analyses show a distinct double-line Hammett relationship with similar slopes and excellent linearity (R-22 of 0.9960.999) in all four ILs. This could be rationalized by a resonance enhanced effect of the IL cation to solvate the para substituent of feasible electronic structure (CSAR effect), revealing a typical and rarely seen ionic liquid effect.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据