期刊
ORGANIC LETTERS
卷 16, 期 21, 页码 5604-5607出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol502656g
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资金
- National Natural Science Foundation of China [21272148, 21472121, 21272147]
- Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, Chinese Academy of Science
Multicomponent cascade cycloaddition of tropone, allenoate, and isocyanide has been disclosed. This method allows for the rapid construction of a highly unusual tricyclic skeleton in an efficient manner. The proposed transformation proceeds through [8 + 2 + 1] cycloaddition, [1,5]-H shift, and cyclization followed by an alkoxy group migration process.
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