期刊
ORGANIC LETTERS
卷 16, 期 8, 页码 2208-2211出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol500723s
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-
资金
- National Research Foundation of Korea (NRF) [NRF-2011-0016344, NRF-2009-0083525]
A new catalytic reaction in which all the atoms of a formamide are incorporated into the product through a formal stereoselective 1,2-insertion of rhodium(II) azavinyl carbenes, generated in situ from readily available N-sulfonylated 1,2,3-triazoles, into the C=O bond of DMF and other N,N-disubstituted formamides to afford cis-diamino enones is described.
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