期刊
ORGANIC LETTERS
卷 16, 期 13, 页码 3540-3543出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol501493h
关键词
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资金
- National Natural Science Foundation of China [21101080]
- Natural Science Foundation of Jiangsu Province [BK2011144]
- Fundamental Research Funds for the Central Universities of China [2014ZZ0047]
- Distinguished talent program of SCUT
A novel straightforward synthesis of both symmetrical and unsymmetrical 2,4-disubstituted-1,3,5-triazines via aerobic copper-catalyzed cyclization of amidines with DMF as a one-carbon synthon has been developed. The presented method allows synthesizing the products that are currently inaccessible or challenging to prepare with the advantages of operational simplicity, broad substrate scope, and no need for prefunctionalized reagents, making it a highly practical approach to access various 2,4-disubstituted-1,3,5-triazines.
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