期刊
ORGANIC LETTERS
卷 17, 期 2, 页码 250-253出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol503329g
关键词
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资金
- Spanish Ministerio de Economia y Competitividad [CTQ2011-23620]
- Generalitat de Catalunya [2014SGR-234]
- IRB Barcelona
- Generalitat de Catalunya
The asymmetric intermolecular and catalytic PausonKhand reaction has remained an elusive goal since Khand and Pauson discovered this transformation. Using a novel family of P-stereogenic phosphanes, we developed the first catalytic system with useful levels of enantioselection for the reaction of norbornadiene and trimethylsilylacetylene. The results demonstrate that Cobisphosphane systems are sufficiently reactive and that they lead to high selectivity in the intermolecular process.
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