期刊
ORGANIC LETTERS
卷 16, 期 14, 页码 3644-3647出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol501284s
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资金
- NSF [CHE-0619638]
- National Institutes of Health [R01-GM84994]
- Bristol-Myers Squibb
- Eli Lilly
- Amgen
- NSF
- Research Corporation for Science Advancement
Although interest in cyclotriveratrylene and its analogues has been significant, limitations in the ability to adjust its structure fully have hampered studies into their complete range of properties. A unique strategy to synthesize a previously unobtainable cyclotriveratrylene analogue and a procedure which adjusts the inner methylene bridges of that material to a triketone is reported. A second triketone synthesis and computational studies indicate the parameters needed for success.
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