期刊
ORGANIC LETTERS
卷 16, 期 17, 页码 4634-4637出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol502225p
关键词
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资金
- Japan Society for the Promotion of Science (JSPS) [23550059, 26410057]
- Grants-in-Aid for Scientific Research [23550059, 26410057] Funding Source: KAKEN
A sequence of oxidation reactions of alkenamides with hypervalent iodine is described. Oxidation of ortho-alkenylbenzamide substrates selectively gave isochroman-1-imine products. The products underwent further oxidation in the presence of a Pd salt catalyst leading to regioselective C-H acetoxylation at the 8-position. A series of oxidations was applied to the crucial steps of asymmetric synthesis of 4-hydroxymellein derivatives.
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