4.8 Article

Co-Catalyzed Synthesis of 1,4-Dicarbonyl Compounds Using TBHP Oxidant

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ORGANIC LETTERS
卷 16, 期 7, 页码 1932-1935

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AMER CHEMICAL SOC
DOI: 10.1021/ol5004687

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  1. Natural Science Foundation of China [21272165]

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A Co-catalyzed reaction for the construction of 1,4-dicarbonyls has been reported in which cascade organo-cobalt addition/trapping/Kornblum-DeLaMare rearrangement were involved. In view of the easy availability of starting materials, wide substrate scope, high functionality tolerance, and operational simplicity, this protocol constituted a simple, practical, and powerful alternative compared with previous approaches.

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