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卷 16, 期 16, 页码 4272-4275出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol501997n
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- Nanyang Technological University
- Singapore Ministry of Education
- LKY PDF
- Ecole Polytechnique
- University of Strasbroug
Radical perfluoroalkylation of alpha-(biaryl-2-yl)vinyl azides is capable of supplying polyfluoroalkyl aza-polycyclic aromatic hydrocarbons (aza-PAHs). Commercially available Me3SiRf (R-f = CF3, C2F5, and C3F7) are employed as the sources of perfluoroalkyl radicals upon oxidation with PhI(OAc)(2). The addition of perfluoroalkyl radicals to biarylvinyl azides generates the corresponding iminyl radicals, which subsequently cyclize with the intramolecular arene moiety, furnishing aza-PAH skeletons having polyfluoroalkyl (RfCH2) function.
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