期刊
ORGANIC LETTERS
卷 16, 期 6, 页码 1818-1821出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol500569b
关键词
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资金
- MEXT, Japan [25410039, 24350023]
- Toyoaki Schlorship Foundation
- Grants-in-Aid for Scientific Research [25410039] Funding Source: KAKEN
Silylethynyl substituents are proposed as protecting groups for porphyrin derivatives to enhance their solubility and enable regioselective functionalization. After usage as protecting groups, silylethynyl groups at the mesa-positions can be efficiently removed upon heating with aqueous H2SO4 in the presence of a surfactant. This approach was applied to the preparation of unsymmetrically beta-substituted porphyrins and porphin-porphyrin oligomers, which were inaccessible by conventional methods.
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