4.8 Article

Synthesis of π-Extended Dibenzophospholes by Intramolecular Radical Cyclization and Their Properties

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ORGANIC LETTERS
卷 16, 期 12, 页码 3228-3231

出版社

AMER CHEMICAL SOC
DOI: 10.1021/ol501189u

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资金

  1. Global COE Program for Chemistry Innovation
  2. MEXT [20685005, 21108507]
  3. Grants-in-Aid for Scientific Research [20685005, 21108507, 25410052] Funding Source: KAKEN

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Intramolecular radical cyclization of phosphine oxides ((RRP)-R-1-P-2(O)H) induced by radical generators affords the corresponding dibenzophosphole oxides in excellent yields. By applying this method, linearly pi-extended ladder-type dibenzophosphole oxides were successfully synthesized.

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