期刊
ORGANIC LETTERS
卷 16, 期 10, 页码 2680-2683出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol500954j
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资金
- National Natural Science Foundation of China [21125208, 21032003]
- National Basic Research Program of China [2010CB833300]
A chiral phosphoric acid catalyzed asymmetric transfer hydrogenation of aromatic amines, quinolin-3-amines, was successfully developed with up to 99% ee. To supplement our previous work on the Ir-catalyzed asymmetric hydrogenation of 2-alkyl substituted quinolin-3-amines, a number of 2-aryl substituted substrates were reduced to provide a series of valuable chiral exocyclic amines with high diastereo- and enantioselectivities.
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