期刊
ORGANIC LETTERS
卷 15, 期 7, 页码 1576-1579出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol400358f
关键词
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资金
- MICINN [CTQ2010-16088/BQU]
- MEC (FPU)
- AGAUR [SGR 47]
- Beatriu de Pinos postdoctoral fellowship
- Wenner-Gren Foundation (postdoctoral fellowship)
- ICIQ Foundation
The gold(I)-catalyzed [2 + 2] cycloaddition of large 1,n-enynes (n = 10-16) provides access to 9- to 15-membered ring macrocycles incorporating a cyclobutene moiety. The reaction requires the use of a gold(I) catalyst bearing a sterically hindered biphenylphosphine ligand.
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