期刊
ORGANIC LETTERS
卷 15, 期 16, 页码 4194-4197出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol401906q
关键词
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资金
- Ministry of Education, Culture, Sports, Science, and Technology in Japan, Iodine Research Project in Chiba University [25105710]
- Grants-in-Aid for Scientific Research [24750033] Funding Source: KAKEN
A variety of methylarenes were successfully converted into the corresponding aromatic nitriles in good to moderate yields by the treatment with NBS or DBDMH in the presence of a catalytic amount of AIBN or BPO, followed by the reaction with molecular iodine in aq NH3 in a one-pot procedure. The present reaction is a useful and practical transition-metal-free method for the preparation of aromatic nitriles from methylarenes.
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