4.8 Article

Release of Guests from Encapsulated Masked Hydrophobic Precursors by a Phototrigger

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ORGANIC LETTERS
卷 15, 期 17, 页码 4374-4377

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AMER CHEMICAL SOC
DOI: 10.1021/ol4019024

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资金

  1. National Science Foundation [NSF-CHE-0848017]
  2. Direct For Mathematical & Physical Scien
  3. Division Of Chemistry [0848017] Funding Source: National Science Foundation

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Examples of release of organic acids from encapsulated p-methoxyphenacyl esters provided here demonstrate the value of a phototrigger strategy to release chemicals of interest in water from hydrophobic precursors. In this study, a photochemical beta-cleavage process centered on the p-methoxyphenacyl group is exploited to release the acid of interest from a water-soluble capsule made up of octa acid.

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