期刊
ORGANIC LETTERS
卷 15, 期 8, 页码 1791-1793出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol4005068
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资金
- JST
- ACT-C
- Ministry of Education, Culture, Sports, Science, and Technology, Japan
- Grants-in-Aid for Scientific Research [21106001, 23655035, 21106005, 23350017] Funding Source: KAKEN
Nickel-catalyzed intermolecular [3 + 2] cycloaddition of vinylcyclopropanes to imines has been developed. This transformation generates substituted pyrrolidines in high yields, with good regio- and diastereo- selectivity under mild reaction conditions. A variety of imines can be used in this reaction. An asymmetric variant of the reaction has also been demonstrated.
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