期刊
ORGANIC LETTERS
卷 16, 期 1, 页码 262-265出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol4032683
关键词
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资金
- National Natural Science Foundation of China [21072047, 21172059, 21272059, 21202039, 21372066]
- Excellent Youth Foundation of Henan Scientific Committee [114100510012]
- Program for Innovative Research Team from the University of Henan Province [2012IRTSTHN006]
- Program for Changjiang Scholars and Innovative Research Team in the University [IRT1061]
- Program for Science & Technology Innovation Talents in Universities of Henan Province [13HASTIT013]
A highly regioselective three-component domino Heck-Negishi coupling reaction has been developed. Organozinc reagents are used to trap an alkylpalladium intermediate of olefins for a first example in the domino Heck reaction. This reaction is applicable to acrylates (or acrylamides) and purine compounds, producing a series of novel purine compounds with carbon substituents at the C6 position in moderate to good yields.
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