期刊
ORGANIC LETTERS
卷 15, 期 21, 页码 5598-5601出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol402837u
关键词
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资金
- MESR (Ministere de l'Enseignement Superieur et de la Recherche)
- Region Haute-Normandie (CRUNCH program)
- CNRS
- University of Rouen
- INSA of Rouen
- ERDF
- project BIOFLUORG [32819]
- LABEX SynORG
The synthesis of highly functionalized monofluorinated cyclopropanes based on a Michael Initiated Ring Closure (MIRC) reaction has been developed. The addition of quaternary ammonium salts derived from ethyl bromofluoroacetate on a panel of electron deficient alkenes followed by cyclization gave rise to an efficient access to monofluorinated cyclopropanes with good yields and remarkable diastereoselectivity.
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