期刊
ORGANIC LETTERS
卷 15, 期 23, 页码 5982-5985出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol4028418
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资金
- Technische Universitat Dortmund
The total synthesis of (-)-ecklonialactone B as well as the 9,10-dihydro derivative by two different strategies is reported. The catalytic asymmetric Claisen rearrangement of Gosteli-type allyl vinyl ethers delivered elaborated alpha-keto ester building blocks. Ring-closing metatheses, including a notable diastereotopos-differentiating variant, a B-alkyl Suzuki-Miyaura cross-coupling reaction and a regio- and diastereoselective last-step epoxidation are key contributors.
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